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docs/src/manuals/user_guide/models.md

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# PXD model
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In the following, all the symbols that are not introduced directly in the text are collected in the table at the end of
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the page
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In the following, all the symbols that are not introduced directly in the text are collected in the table at the
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[end](@ref "Symbol list") of the page
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## Electrolyte
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The mass and charge conservation in the electrolyte are given by
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```math
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```
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The volumetric reaction rate is given as ``R_\text{elyte} = -\sum_\text{elde} \gamma_\text{elde} R_\text{elde}`` where ``\gamma_{\text{elde}}`` is the volumetric surface area and the expression for ``R_\text{elde}`` is given below. Note that the reaction rates depends on the spatial variable ``x``. For the chemical potential, we use ``\mu = 2RT\log(c_\text{elyte})``. The effective quantities are computed from the intrinsic properties and the volume fraction using a Bruggemann coefficient, denoted ``b``, which yields ``\kappa_{\text{elyte},\text{eff}} = \varepsilon_\text{elyte}^{b}\kappa_{\text{elyte}}`` and ``D_{\text{elyte},\text{eff}} = \varepsilon_\text{elyte}^{b}D_{\text{elyte}}``. For the electrolyte, we have a spatially dependent Bruggeman coefficient.
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## Electrode
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In the electrode, the charge conservation equation is given by
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```math
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-\nabla\cdot (\kappa_{\text{elde}, \text{eff}} \nabla \phi_\text{elde}) = F\gamma_\text{elde} R_{\text{elde}}.
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- 4\pi r_p^2 D_\text{elde} \frac{\partial c_\text{elde}}{\partial r}(t, x, r_p) = \frac{\gamma_\text{elde} R_\text{elde}}{\varepsilon_\text{elde}}\frac{4\pi r_p^3}{3}.
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```
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Reaction kinetics. The reaction rate ``R_\text{elde}`` at each electrode is given
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## Reaction kinetics
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The reaction rate ``R_\text{elde}`` at each electrode is given
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```math
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R_\text{elde} = j_{\text{elde}}(c_\text{elde}, c_\text{elyte}, T)(e^{\alpha F\frac{\eta_\text{elde}}{RT}} - e^{-(1 - \alpha) F\frac{\eta_\text{elde}}{RT}} ) .
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```
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j_\text{elde} = k_{\text{elde},0} e^{-\frac{E_a}{R}(1/T - 1/T_{\text{ref}})}\left(c_\text{elyte}(c_{\text{elde},\max} - c_\text{elde})c_\text{elde}\right)^{\frac12}.
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```
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## Symbol list
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| Symbol | Definition |
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|---------------------------------------------|-------------------------------------------------|
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| ``c_\text{elyte}``, ``c_\text{elde}`` | Lithium concentration in electrolyte, electrode |

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