After #3914 RTD now builds multiple PDF-LaTeX files at the last step - only for the Latest type of doc build, since that's the only one we build tex files in, and consequently complains only one file is permitted.
Build fail: https://app.readthedocs.org/projects/esmvaltool/builds/30090808/
Example of previous fix (possibly related, according to @bouweandela ): #4197