add training reactions from Nitrogen library with coverage_dependence

Author: Tingchenlee

input/kinetics/families/Surface_Adsorption_Single/training/reactions.py

@@ -270,3 +270,32 @@
     facet = "111",
 )
 
+entry(
+    index = 12,
+    label = "X + NO <=> NO_X",
+    degeneracy = 1.0,
+    kinetics = StickingCoefficient(A=0.85, n=0, Ea=(0,'J/mol'), T0=(1,'K'), Tmin=(200,'K'), Tmax=(3000,'K')),
+    rank = 3,
+    shortDesc = u"""Surface_Adsorption_Single""",
+    longDesc = """
+    Detailed surface reaction mechanism for Pt-catalyzed abatement of automotive exhaust gases
+    Deutschmann et al. (2009)
+    doi:10.1016/j.apcatb.2009.05.006
+    """,
+    metal = "Pt",
+)
+
+entry(
+    index = 13,
+    label = "X + NO2 <=> NO2X",
+    degeneracy = 2.0,
+    kinetics = StickingCoefficient(A=0.9, n=0, Ea=(0,'J/mol'), T0=(1,'K'), Tmin=(200,'K'), Tmax=(3000,'K')),
+    rank = 3,
+    shortDesc = u"""Surface_Adsorption_Single""",
+    longDesc = """
+    Detailed surface reaction mechanism for Pt-catalyzed abatement of automotive exhaust gases
+    Deutschmann et al. (2009)
+    doi:10.1016/j.apcatb.2009.05.006
+    """,
+    metal = "Pt",
+)

input/kinetics/families/Surface_Dissociation/training/reactions.py

@@ -1601,3 +1601,26 @@
     facet = "0001",
 )
 
+entry(
+    index = 65,
+    label = "NOX + OX <=> NO2X + X_4",
+    degeneracy = 1.0,
+    kinetics = SurfaceArrhenius(
+        A = (1.3e17, 'cm^2/(mol*s)'), 
+        n = 0.0,
+        Ea = (133, 'kJ/mol'),
+        T0=(1,'K'),   
+        Tmin = (200, 'K'),
+        Tmax = (3000, 'K'),
+        coverage_dependence = {'CO_X': {'a':0.0, 'm':0.0, 'E':(75, 'kJ/mol')}},
+    ),
+    rank = 3,
+    shortDesc = u"""Surface_Dissociation""",
+    longDesc = """
+    Detailed surface reaction mechanism for Pt-catalyzed abatement of automotive exhaust gases
+    Deutschmann et al. (2009)
+    doi:10.1016/j.apcatb.2009.05.006
+    """,
+    metal = "Pt",
+)
+