diff --git a/Project.toml b/Project.toml
index 48765eb2..fd26fbb7 100644
--- a/Project.toml
+++ b/Project.toml
@@ -4,23 +4,26 @@ authors = ["Vedant Puri <vedantpuri@gmail.com>"]
 version = "1.6.0"
 
 [deps]
+Accessors = "7d9f7c33-5ae7-4f3b-8dc6-eff91059b697"
 ArrayInterface = "4fba245c-0d91-5ea0-9b3e-6abc04ee57a9"
 DocStringExtensions = "ffbed154-4ef7-542d-bbb7-c09d3a79fcae"
 LinearAlgebra = "37e2e46d-f89d-539d-b4ee-838fcccc9c8e"
 MacroTools = "1914dd2f-81c6-5fcd-8719-6d5c9610ff09"
-Accessors = "7d9f7c33-5ae7-4f3b-8dc6-eff91059b697"
 
 [weakdeps]
+ChainRulesCore = "d360d2e6-b24c-11e9-a2a3-2a2ae2dbcce4"
 SparseArrays = "2f01184e-e22b-5df5-ae63-d93ebab69eaf"
 StaticArraysCore = "1e83bf80-4336-4d27-bf5d-d5a4f845583c"
 
 [extensions]
+SciMLOperatorsChainRulesCoreExt = "ChainRulesCore"
 SciMLOperatorsSparseArraysExt = "SparseArrays"
 SciMLOperatorsStaticArraysCoreExt = "StaticArraysCore"
 
 [compat]
 Accessors = "0.1.42"
 ArrayInterface = "7.19"
+ChainRulesCore = "1.26.0"
 DocStringExtensions = "0.9.4"
 LinearAlgebra = "1.10"
 MacroTools = "0.5.16"
diff --git a/ext/SciMLOperatorsChainRulesCoreExt.jl b/ext/SciMLOperatorsChainRulesCoreExt.jl
new file mode 100644
index 00000000..ec292983
--- /dev/null
+++ b/ext/SciMLOperatorsChainRulesCoreExt.jl
@@ -0,0 +1,53 @@
+module SciMLOperatorsChainRulesCoreExt
+
+using SciMLOperators
+using ChainRulesCore
+import SciMLOperators: ScaledOperator, ScalarOperator, AbstractSciMLOperator
+
+"""
+Fix for gradient double-counting issue in ScaledOperator constructor.
+
+The issue: When creating ScaledOperator(λ, L) where λ is a ScalarOperator with parameter 
+dependencies, Zygote was double-counting gradients because:
+1. Gradient flows through the ScalarOperator's creation/value
+2. Gradient also flows through the ScalarOperator being stored as a struct field
+
+This rrule ensures gradients are only counted once by carefully managing the pullback
+to avoid the structural dependency double-counting.
+
+Fixes issue: https://github.com/SciML/SciMLOperators.jl/issues/305
+"""
+function ChainRulesCore.rrule(::Type{ScaledOperator}, λ::ScalarOperator, L::AbstractSciMLOperator)
+    # Forward pass - same as original constructor
+    result = ScaledOperator(λ, L)
+    
+    function ScaledOperator_pullback(Ȳ)
+        # Handle gradients carefully to avoid double-counting for ScalarOperator
+        # The key insight: gradients should flow through ScalarOperator creation
+        # but NOT through struct field access
+        
+        if hasfield(typeof(Ȳ), :λ) && getfield(Ȳ, :λ) isa ChainRulesCore.AbstractTangent
+            λ_tangent = getfield(Ȳ, :λ)
+            # For ScalarOperator, only propagate through the value to avoid double-counting
+            if hasfield(typeof(λ_tangent), :val)
+                ∂λ = ChainRulesCore.Tangent{typeof(λ)}(val=getfield(λ_tangent, :val))
+            else
+                ∂λ = λ_tangent
+            end
+        else
+            ∂λ = NoTangent()
+        end
+        
+        if hasfield(typeof(Ȳ), :L) && getfield(Ȳ, :L) isa ChainRulesCore.AbstractTangent
+            ∂L = getfield(Ȳ, :L)
+        else
+            ∂L = NoTangent()
+        end
+        
+        return (NoTangent(), ∂λ, ∂L)
+    end
+    
+    return result, ScaledOperator_pullback
+end
+
+end # module
\ No newline at end of file
diff --git a/test/chainrules.jl b/test/chainrules.jl
new file mode 100644
index 00000000..153afe64
--- /dev/null
+++ b/test/chainrules.jl
@@ -0,0 +1,119 @@
+# Tests for ChainRules extension fixing gradient double-counting issue
+# These tests specifically target issue #305
+
+using SciMLOperators
+using LinearSolve, Zygote, Test
+using SciMLOperators: ScaledOperator
+
+@testset "ChainRules fix for ScalarOperator gradient double-counting" begin
+    # Test 1: Simple ScaledOperator creation
+    @testset "Simple ScaledOperator gradient" begin
+        simple_func = p -> 2.0 * p
+        
+        # Create ScalarOperator and matrix operator
+        S = ScalarOperator(0.0, (A, u, p, t) -> simple_func(p))
+        M = MatrixOperator(ones(2, 2))
+        
+        # Test that ScaledOperator creation doesn't double-count gradients
+        function test_scaled(p)
+            S_val = ScalarOperator(simple_func(p))
+            scaled = S_val * M
+            return scaled.λ.val
+        end
+        
+        p_val = 0.5
+        result = test_scaled(p_val)
+        grad = Zygote.gradient(test_scaled, p_val)[1]
+        
+        @test result ≈ simple_func(p_val)
+        @test grad ≈ 2.0  # Should not be doubled (4.0)
+    end
+    
+    # Test 2: Full update_coefficients pipeline
+    @testset "update_coefficients pipeline" begin
+        exp_func = p -> exp(1 - p)
+        
+        A1 = MatrixOperator(rand(3, 3))
+        A2 = MatrixOperator(rand(3, 3))
+        Func = ScalarOperator(0.0, (A, u, p, t) -> exp_func(p))
+        A = A1 + Func * A2
+        
+        # Test that update_coefficients doesn't cause gradient doubling
+        function test_update(p)
+            A_updated = update_coefficients(A, 0, p, 0)
+            # Access the scalar value from the updated composition
+            scaled_op = A_updated.ops[2]  # This should be the ScaledOperator
+            return scaled_op.λ.val
+        end
+        
+        p_val = 0.3
+        result = test_update(p_val)
+        grad = Zygote.gradient(test_update, p_val)[1]
+        
+        @test result ≈ exp_func(p_val)
+        # Check that gradient matches the derivative of exp_func
+        expected_grad = -exp(1 - p_val)  # derivative of exp(1-p) is -exp(1-p)
+        @test grad ≈ expected_grad
+    end
+    
+    # Test 3: Original MWE from issue #305
+    @testset "Original MWE from issue #305" begin
+        a1 = rand(3, 3)
+        a2 = rand(3, 3)
+        func = p -> exp(1 - p)
+        a = p -> a1 + func(p) * a2
+        
+        A1 = MatrixOperator(a1)
+        A2 = MatrixOperator(a2)
+        Func = ScalarOperator(0.0, (A, u, p, t) -> func(p))
+        A = A1 + Func * A2
+        
+        b = rand(3)
+        
+        function sol1(p)
+            Ap = update_coefficients(A, 0, p, 0) |> concretize
+            prob = LinearProblem(Ap, b)
+            sol = solve(prob, KrylovJL_GMRES())
+            return sum(sol.u)
+        end
+        
+        function sol2(p)
+            Ap = a(p)
+            prob = LinearProblem(Ap, b)
+            sol = solve(prob, KrylovJL_GMRES())
+            return sum(sol.u)
+        end
+        
+        p_val = rand()
+        s1, s2 = sol1(p_val), sol2(p_val)
+        
+        # Primal solutions should match
+        @test s1 ≈ s2
+        
+        grad1 = Zygote.gradient(sol1, p_val)[1]
+        grad2 = Zygote.gradient(sol2, p_val)[1]
+        
+        # Gradients should match (no more doubling)
+        @test grad1 ≈ grad2 rtol=1e-10
+        @test !(grad1 ≈ 2 * grad2)  # Should NOT be doubled anymore
+    end
+    
+    # Test 4: Direct ScaledOperator constructor (the specific case our rrule fixes)
+    @testset "Direct ScaledOperator constructor" begin
+        func = p -> 3.0 * p
+        
+        function test_direct_constructor(p)
+            S = ScalarOperator(func(p))
+            M = MatrixOperator([2.0 1.0; 1.0 2.0])
+            scaled = ScaledOperator(S, M)  # This should use our rrule
+            return scaled.λ.val
+        end
+        
+        p_val = 0.5
+        result = test_direct_constructor(p_val)
+        grad = Zygote.gradient(test_direct_constructor, p_val)[1]
+        
+        @test result ≈ func(p_val)
+        @test grad ≈ 3.0  # Should not be doubled (6.0)
+    end
+end
\ No newline at end of file