diff --git a/src/Instrumentation/Guzzle/src/GuzzleInstrumentation.php b/src/Instrumentation/Guzzle/src/GuzzleInstrumentation.php
index ace1c622b..fd70c503d 100644
--- a/src/Instrumentation/Guzzle/src/GuzzleInstrumentation.php
+++ b/src/Instrumentation/Guzzle/src/GuzzleInstrumentation.php
@@ -6,6 +6,7 @@
 
 use function get_cfg_var;
 use GuzzleHttp\Client;
+use GuzzleHttp\Exception\BadResponseException;
 use GuzzleHttp\Promise\PromiseInterface;
 use OpenTelemetry\API\Globals;
 use OpenTelemetry\API\Instrumentation\CachedInstrumentation;
@@ -120,6 +121,12 @@ public static function register(): void
                         return $response;
                     },
                     onRejected: function (\Throwable $t) use ($span) {
+                        if ($t instanceof BadResponseException && $t->hasResponse()) {
+                            $response = $t->getResponse();
+                            $span->setAttribute(TraceAttributes::HTTP_RESPONSE_STATUS_CODE, $response->getStatusCode());
+                            $span->setAttribute(TraceAttributes::NETWORK_PROTOCOL_VERSION, $response->getProtocolVersion());
+                            $span->setAttribute(TraceAttributes::HTTP_RESPONSE_BODY_SIZE, $response->getBody()->getSize());
+                        }
                         $span->recordException($t);
                         $span->setStatus(StatusCode::STATUS_ERROR, $t->getMessage());
                         $span->end();
diff --git a/src/Instrumentation/Guzzle/tests/Integration/GuzzleInstrumentationTest.php b/src/Instrumentation/Guzzle/tests/Integration/GuzzleInstrumentationTest.php
index 64fdc8ccc..ca951949e 100644
--- a/src/Instrumentation/Guzzle/tests/Integration/GuzzleInstrumentationTest.php
+++ b/src/Instrumentation/Guzzle/tests/Integration/GuzzleInstrumentationTest.php
@@ -6,6 +6,7 @@
 
 use ArrayObject;
 use GuzzleHttp\Client;
+use GuzzleHttp\Exception\ConnectException;
 use GuzzleHttp\Handler\MockHandler;
 use GuzzleHttp\HandlerStack;
 use GuzzleHttp\Promise\PromiseInterface;
@@ -165,4 +166,47 @@ public function test_headers_propagation(): void
         $this->client->get('/');
 
     }
+
+    /**
+     * @dataProvider exceptionProvider
+     */
+    public function test_exceptions_enabled_sets_response_attributes($response, ?int $expected = null): void
+    {
+        $client = new Client([
+            'handler' => $this->handlerStack,
+            'base_uri' => 'https://example.com/',
+            'http_errors' => true,
+            'exceptions' => true,
+        ]);
+        $this->mock->append($response);
+        $this->assertCount(0, $this->storage);
+
+        try {
+            $client->send(new Request('GET', 'https://example.com/error'));
+        } catch (\Exception $e) {
+            // Expected exception
+        }
+        $this->assertCount(1, $this->storage);
+        $span = $this->storage->offsetGet(0);
+        $attributes = $span->getAttributes()->toArray();
+        if ($expected) {
+            $this->assertSame($expected, $attributes[TraceAttributes::HTTP_RESPONSE_STATUS_CODE]);
+            $this->assertGreaterThan(0, $attributes[TraceAttributes::HTTP_RESPONSE_BODY_SIZE]);
+            $this->assertArrayHasKey(TraceAttributes::NETWORK_PROTOCOL_VERSION, $attributes);
+        } else {
+            $this->assertArrayNotHasKey(TraceAttributes::HTTP_RESPONSE_STATUS_CODE, $attributes);
+        }
+    }
+
+    public static function exceptionProvider(): array
+    {
+        return [
+            '400 Bad Request' => [new Response(400, [], 'Bad Request'), 400],
+            '404 Not Found' => [new Response(404, [], 'Not Found'), 404],
+            '500 Internal Server Error' => [new Response(500, [], 'Internal Server Error'), 500],
+            '503 Service Unavailable' => [new Response(503, [], 'Service Unavailable'), 503],
+            'network connection error' => [new ConnectException('network error', new Request('GET', 'https://example.com/error'))],
+            'runtime exception' => [new \RuntimeException('runtime error')],
+        ];
+    }
 }