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electron.txt
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COMPILATION OF ELECTRON CROSS SECTIONS USED BY A. V. PHELPS
Please refer to these data using the sources cited for each gas.
Please do not refer to any of them as "JILA cross sections",
because a) the data shown here for a given gas may come from
several sources that should be referred to by the respective
authors names; b) in most cases no one else at JILA or NIST has
approved the data or even looked at it. Reference to this data as
"JILA data" could be interpreted incorrectly as indicating NIST
approval and could jepordize my Web site usage.
GASES COMPILED: O2, N2, CO, CO2, H2, H2O, NO, SF6, He, Ne, Ar,
Xe, Na, and Mg
Comments are made on cross sections from other sources for some
of these and other gases.
WE MAKE NO CLAIMS FOR THESE CROSS SECTIONS BEYOND THOSE STATED IN
THE PAPERS WHERE THEY ARE PUBLISHED OR CITED. IN MOST CASES THESE
CROSS SECTIONS WERE ASSEMBLED IN THE 1970'S AND 1980'S. IN ONLY A
FEW CASES HAVE THEY BEEN MODIFIED OR TESTED SINCE THAT TIME. I DO
NOT PLAN ANY UPDATES. ADDITIONS HAVE BEEN MADE WHEN CROSS
SECTIONS HAVE BEEN ASSEMBLED FOR OTHER PURPOSES. SINCE THE JILA
INFORMATION CENTER WAS CLOSED BY NIST, THERE IS NO ONE THERE TO
HELP YOU. OPINIONS EXPRESSED ARE THOSE OF A. V. PHELPS AND DO NOT
IMPLY JILA, CU, OR NIST APPROVAL.
The cross sections are in 1E-16 cm2. The two-term Boltzmann code,
BACKPRO, used in deriving our cross sections employs linear
interpolation between points in the cross section tables.
Therefore linear interpolation should be applied when using them.
Except as noted below for N2, the cross sections listed in JILA
Information Center Reports 26, 27, and 28 for N2, H2, and O2
should be the same as those listed here. (This aspect has not
been checked in detail, so please inform me of discrepancies.)
It should be kept in mind that the momentum transfer cross sections
tabulated are effective values that include the effects of inelastic
collisions as is appropriate for use in the two-tern spherical harmonic
expansion. See, for example, Baraff and Buchsbaum, Phys. Rev. 130,
1007 (1963) and Sec. IIB of Pitchford and Phelps, Phys. Rev. A 25,
540 (1982). Where data is available, the effective Qm is set
equal to the sum of the inelastic cross sections plus the elastic
momentum transfer cross section. This is an approximate relation.
Some of the terms used in the tables and the BACKPRO code are:
QSCALE is a factor by which the input cross sections from the
various sources were multiplied to get the values shown here
and used in the Boltzmann equation.
ENERGY LOSS is the inelastic energy loss in eV.
LOWER LIMIT and UPPER LIMIT were used by BACKPRO to limit
the range within which the tables were interpolated.
Interpolation was the most time-consuming step in the code.
EBR is a parameter used to describe the sharing of energy
among the two electrons resulting from ionization. It is
the parameter w in Yoshida, Phelps, and Pitchford, Phys. Rev.
27, 1345 (1983) and its choice is based on the data of Opal,
Peterson, and Beaty, Phys. Rev. 55, 4100 (1971).
BACKPRO is the FORTRAN code for the solution of the electron
Boltzmann equation developed by Frost and Phelps, Phys. Rev.
127, 1621 (1962) and modified by Phelps and coworkers in later
papers. A detailed analysis of the code as of 1975 has been
given by P.H. Luft, JILA Information Center Report No. 14,
October 1975. Changes since then are minimally documented,
but include accounting for the electrons produced by electron
impact ionization during either a spatial or temporal
exponential growth. See Yoshida et al as cited above.
These cross sections were derived to give a good fit
to published electron transport, excitation coefficient,
attachment coefficient, and ionization coefficient data
for the pure gases. In many cases they have been tested
satisfactorily against similar swarm data for gas mixtures,
e.g., CO2 laser mixtures, H2-Ar mixtures, N2-SF6 mixtures,
and atmospheric pressure dry and moist air. In several
cases, e.g., He, Ar, and Xe, we have not attempted to
distinguish among the various excited states and find the
cross sections satisfactory for models of mixtures and of
ionization and transport in the pure gases.
Please refer to the published articles where possible.
Also, please inform me of any errors or inconsistencies.
Original file preparation 10/29/95.
Last revision of file 05/21/05.
A. V. Phelps, Retired
JILA
University of Colorado
Boulder, CO 80309-0440
e-mail: avp@jila.colorado.edu
General remarks on electron collision cross sections:
For a recent review of electron cross sections see:
T. D. Mark, Y. Hatano, and F. Linder, "Electron Collision
Cross Sections" in "Atomic and molecular data for
radiotherapy and radiation research" IAEA-TECDOC-799, May
1995, Chapt. 2. This chapter contains graphical compilations
of cross sections for Ne, Ar, H2, H2O, CO2, CH4, and C3H8.
These cross sections have not been compared to those given
in this file.
M. Hayashi has prepared very extensive bibliographies of papers on
electron collisions with Ar, H2, O2, N2, CO, H2O, halogen
molecules, hydrogen halide molecules, CO2, CH4, NH3, and PH3. Some
of these reoprts contain recommended cross sections. Available
reports are entitled "Bibliography of electron and photon
cross sections with atoms and molecules published in the 20th century
- [name of gas] -", National Institute for Fusion Research, Report
NIFS-Data Series NIFS-DATA-[??]. Unfortunately, the cross sections
are not available on the Web
Very extensive reviews and compilations of published electron-atom
and electron-molecule cross sections have been prepared by A.
Zecca, G. P. Karwasz, and Brusa, Riv. Nuovo Cimento 19, No. 3,
1-146 (1996) and G. P. Karwasz, R. S. Brusa, and A. Zecca, Riv.
Nuovo Cimento 24, No. 1, 1-118 (2001) and No. 4, 1-101 (2001).
Data shown are selected on the basis of “perceived quality”,
but no recommended values are given. Apparently floppy disk(s?)
giving tabulations can be purchased from the Italian Physical
Society. I have not seen the disks, i.e., they are too expensive.
Unfortunately for gas discharge modeling, the data ranges in
the review papers are limited, especially for momentum transfer
cross sections that can differ greatly from "total" cross sections
at the higher energies.
Stephen Biagi at sfb@hep.ph.liv.ac.uk has derived a sets of
cross sections for electron collisions with ~ 50 different gases
that are required to be consistent with electron swarm data. The ~50
gases include: N2, O2, H20, Ar, CO2, He, Ne, H2, D2, CH4, etc.
Unfortunately, the tabulations of these cross sections are not
available on the Web.
A recent review of electron-molecule collisions is
Hotop, Ruf, Allan, and Frabrikant, "Resonances and threshold
phenomena in low energy electron collisions with molecules and
clusters", in Advances in Atomic, Molecular and Optical Physics,
(Elsevier, 2003) Vol. 49.
A review of experimental integrated and differential cross section
data for electron collisions with some diatomic molecules is
Brunger and Buckman, Physics Reports, 357, 215 (2002). The gases
discussed include H2, O2, N2, the halogens,NO, CO, and halogen
halides. This data is tabulated in Landolt-Bornstein, Vol. 17,
Subvol. C, pp. 35-55 (2003). Also, Vol 17, Subvol. A is concerned
with electron and photon collisions with atoms, but I do not have
access to this volume or its data.
GENERAL WARNING TO GAS DISCHARGE MODELERS:
IF AUTHORS DO NOT EXPLICITLY STATE THAT THERE IS AGREEMENT BETWEEN
A) IONIZATION, EXCITATION, ATTACHMMENT (IF APPLICABLE), AND TRANSPORT
COEFFICIENTS CALCULATED USING THEIR CROSS SECTIONS AND B) RELIABLE
EXPERIMENTAL MEASUREMENTS OF THESE COEFFICIENTS, YOU SHOULD BE
VERY SKEPTICAL OF ALL OF THEIR CROSS SECTIONS AND OF ELECTRON
TRANSPORT AND REACTION COEFFICIENT RESULTS DERIVED FROM THEM.
AGREEMENT WITH SWARM EXPERIMENTS SUCH AS IONIZATION COEFFICIENT,
DRIFT VELOCITY, THE RATIO OF THE TRANSVERSE AND LOGITUDINAL DIFFUSION
COEFFICIENT TO MOBILITY, ATTACHMENT COEFFICIENTS, AND EXCITATION
COEFFICIENTS ARE CRICIAL EVIDENCE OF A RELIABLE SET OF INPUT CROSS
SECTIONS FOR MODELING. FOR EACH GAS IN THIS FILE WE HAVE SUMMARIZED
OUR TESTS OF THE CROSS SECTIONS AGAINST EXPERIMENTAL SWARM DATA.
OXYGEN - O2 - 1978
These cross sections are those developed in Lawton and Phelps, J.
Chem. Phys. 69, 1055 (1978). The agreement of the transport
and reaction coefficients is good and is discussed in detail
in this paper. Information Center Report No. 28 is based on
the same computer files as used to assemble the following data.
As of 9/28/01 I know of no reason to change the cross sections.
Note that the "cross sections" listed under the heading of
three-body attrachment are expressed as equivalent cross
sections at an O2 density of 1 molecule/cm3. This means
that the rate coefficients k and spatial attachment
coefficients alpha/n calculated using BACKPRO must be
multiplied by the O2 density in molecules/cm3 to obtain the
equivalent of the two-body coefficients per molecule calculated
for other processes, such as excitation and ionization.
O2 MOMENTUM-TRANSFER CROSS SECTION
ENERGY Effective Qm - Defined in introduction
1 0.0000 0.3500
2 0.0010 0.3500
3 0.0020 0.3600
4 0.0030 0.4000
5 0.0050 0.5000
6 0.0070 0.5800
7 0.0085 0.6400
8 0.0100 0.7000
9 0.0150 0.8700
10 0.0200 0.9900
11 0.0300 1.2400
12 0.0400 1.4400
13 0.0500 1.6000
14 0.0700 2.1000
15 0.1000 2.5000
16 0.1200 2.8000
17 0.1500 3.1000
18 0.1700 3.3000
19 0.2000 3.6000
20 0.2500 4.1000
21 0.3000 4.5000
22 0.3500 4.7000
23 0.4000 5.2000
24 0.5000 5.7000
25 0.7000 6.1000
26 1.0000 7.2000
27 1.2000 7.9000
28 1.3000 7.9000
29 1.5000 7.6000
30 1.7000 7.3000
31 1.9000 6.9000
32 2.1000 6.6000
33 2.2000 6.5000
34 2.5000 6.1000
35 2.8000 5.8000
36 3.0000 5.7000
37 3.3000 5.5000
38 3.6000 5.4500
39 4.0000 5.5000
40 4.5000 5.5500
41 5.0000 5.6000
42 6.0000 6.0000
43 7.0000 6.6000
44 8.0000 7.1000
45 10.0000 8.0000
46 12.0000 8.5000
47 15.0000 8.8000
48 17.0000 8.7000
49 20.0000 8.6000
50 25.0000 8.2000
51 30.0000 8.0000
52 50.0000 7.7000
53 75.0000 6.8000
54 100.0000 6.5000
55 150.0000 6.7000
56 200.0000 6.0000
57 300.0000 4.9000
58 500.0000 3.6000
59 700.0000 2.9000
60 1000.0000 2.1200
61 1500.0000 1.4800
62 2000.0000 1.1400
63 3000.0000 0.7900
64 5000.0000 0.5100
65 7000.0000 0.3800
66 10000.0000 0.2800
O2 THREE-BODY ATTACHMENT
ENERGY LOSS = 0.000 , LOWER LIMIT = 0.000 , UPPER LIMIT = 1.058 ,
QSCALE = 1.000000 (QSCALE USED ONLY FOR RECONSTRUCTING INPUT DATA)
ENERGY CROSS SECTION
1 0.0000 0.0000
2 0.0580 0.0000
3 0.0730 5.6E-21
4 0.0830 18.0E-21
5 0.0890 4.2E-21
6 0.0950 8.4E-21
7 0.1030 18.0E-21
8 0.1090 0.0000
9 0.1500 0.0000
10 0.1700 0.0000
11 0.2000 0.0000
12 0.2100 3.56E-21
13 0.2300 0.0000
14 0.3200 0.0000
15 0.3300 2.30E-21
16 0.3500 0.0000
17 0.4400 0.0000
18 0.4500 1.45E-21
19 0.4700 0.0000
20 0.5600 0.0000
21 0.5700 1.1E-21
22 0.5900 0.0000
23 0.6800 0.0000
24 0.6900 8.0E-22
25 0.7100 0.0000
26 0.7900 0.0000
27 0.8000 7.0E-22
28 0.8200 0.0000
29 0.9000 0.0000
30 0.9100 5.5E-22
31 0.9300 0.0000
32 1.0200 0.0000
33 1.0300 4.2E-22
34 1.0500 0.0000
35 1.5000 0.0000
36 10000.0000 0.0000
O2 TWO-BODY ATTACHMENT
ENERGY LOSS = 0.000 , LOWER LIMIT = 0.000 , UPPER LIMIT = 100.001 ,
QSCALE = 1.200000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 4.4000 0.0000
3 4.9000 0.0000
4 5.3800 0.0023
5 5.8600 0.0072
6 6.1000 0.0108
7 6.4800 0.0138
8 6.7700 0.0152
9 7.0500 0.0156
10 7.3000 0.0148
11 7.5300 0.0131
12 7.7700 0.0110
13 8.0000 0.0084
14 8.2500 0.0054
15 8.7300 0.0028
16 9.2000 0.0014
17 9.6800 0.0008
18 10.1500 0.0008
19 11.3500 0.0008
20 10000.0000 0.0000
O2 SINGL LEVEL ROT PKQ FOR 300K
ENERGY LOSS = 0.020 , LOWER LIMIT = 0.026 , UPPER LIMIT = 1.677 ,
QSCALE = 1.000000
ENERGY CROSS SECTION ENERGY CROSS SECTION
1 0.0000 0.0000
2 0.0067 0.0000
3 0.0700 0.0000
4 0.0800 0.0054
5 0.1000 0.0000
6 0.2000 0.0000
7 0.2100 0.0216
8 0.2200 0.0000
9 0.3200 0.0000
10 0.3300 0.0384
11 0.3500 0.0000
12 0.4400 0.0000
13 0.4500 0.0540
14 0.4700 0.0000
15 0.5600 0.0000
16 0.5700 0.0672
17 0.5900 0.0000
18 0.6800 0.0000
19 0.6900 0.0804
20 0.7100 0.0000
21 0.7900 0.0000
22 0.8000 0.0936
23 0.8100 0.0000
24 0.9000 0.0000
25 0.9100 0.0840
26 0.9300 0.0000
27 1.0200 0.0000
28 1.0300 0.0720
29 1.0500 0.0000
30 1.1300 0.0000
31 1.1400 0.0468
32 1.1600 0.0000
33 1.2300 0.0000
34 1.2300 0.0600
35 1.2600 0.0000
36 1.3400 0.0000
37 1.3500 0.0360
38 1.3700 0.0000
39 1.4400 0.0000
40 1.4500 0.0240
41 1.4700 0.0000
42 1.5400 0.0000
43 1.5500 0.0120
44 1.5700 0.0000
45 1.6400 0.0000
46 1.6500 0.0048
47 1.6700 0.0000
48 10000.0000 0.0000
O2 V=1 LINDER AND SCHMIDT WITH SPLIT PK
ENERGY LOSS = 0.190 , LOWER LIMIT = 0.181 , UPPER LIMIT = 5.005 ,
QSCALE = 2.500000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 0.1900 0.0000
3 0.2000 0.0010
4 0.2100 0.0010
5 0.2300 0.0000
6 0.3200 0.0000
7 0.3300 0.4150
8 0.3500 0.0000
9 0.4400 0.0000
10 0.4500 1.3500
11 0.4700 0.0000
12 0.5600 0.0000
13 0.5700 1.8500
14 0.5900 0.0000
15 0.6800 0.0000
16 0.6900 1.6500
17 0.7100 0.0000
18 0.7900 0.0000
19 0.8000 1.0000
20 0.8200 0.0000
21 0.9000 0.0000
22 0.9100 0.6000
23 0.9300 0.0000
24 1.0200 0.0000
25 1.0300 0.2850
26 1.0500 0.0000
27 1.1300 0.0000
28 1.1400 0.1125
29 1.1600 0.0000
30 1.2300 0.0000
31 1.2400 0.0475
32 1.2600 0.0000
33 1.3400 0.0000
34 1.3500 0.0165
35 1.3700 0.0000
36 1.4400 0.0000
37 1.4500 0.0055
38 1.4700 0.0000
39 1.5400 0.0000
40 1.5500 0.0019
41 1.5700 0.0000
42 1.6300 0.0000
43 1.6500 0.0006
44 1.6700 0.0000
45 3.5000 0.0000
46 4.0000 0.0000
47 5.0000 0.0000
48 10000.0000 0.0000
O2 V=2 LINDER AND SCHMIDT X2
ENERGY LOSS = 0.380 , LOWER LIMIT = 0.439 , UPPER LIMIT = 5.005 ,
QSCALE = 1.250000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 0.3800 0.0000
3 0.4400 0.0000
4 0.4500 0.0000
5 0.4700 0.0000
6 0.5600 0.0000
7 0.5700 0.1400
8 0.5900 0.0000
9 0.6800 0.0000
10 0.6900 0.4150
11 0.7100 0.0000
12 0.7900 0.0000
13 0.8000 0.5350
14 0.8200 0.0000
15 0.9000 0.0000
16 0.9100 0.4650
17 0.9300 0.0000
18 1.0200 0.0000
19 1.0300 0.3150
20 1.0500 0.0000
21 1.1300 0.0000
22 1.1400 0.2000
23 1.1600 0.0000
24 1.2300 0.0000
25 1.2400 0.0950
26 1.2600 0.0000
27 1.3400 0.0000
28 1.3500 0.0400
29 1.3700 0.0000
30 1.4400 0.0000
31 1.4500 0.0185
32 1.4700 0.0000
33 1.5400 0.0000
34 1.5500 0.0085
35 1.5700 0.0000
36 1.6300 0.0000
37 1.6500 0.0034
38 1.6700 0.0000
39 3.5000 0.0000
40 4.0000 0.0000
41 5.0000 0.0000
42 10000.0000 0.0000
O2 V=3 LINDER AND SCHMIDT X2 WITH 9EV RES FRM WONG-TRAJMAR
ENERGY LOSS = 0.570 , LOWER LIMIT = 0.671 , UPPER LIMIT = 44.995 ,
QSCALE = 1.250000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 0.5700 0.0000
3 0.6800 0.0000
4 0.6900 0.0037
5 0.7100 0.0000
6 0.7900 0.0000
7 0.8000 0.0215
8 0.8200 0.0000
9 0.9000 0.0000
10 0.9100 0.0900
11 0.9300 0.0000
12 1.0200 0.0000
13 1.0300 0.1200
14 1.0500 0.0000
15 1.1300 0.0000
16 1.1400 0.1150
17 1.1600 0.0000
18 1.2300 0.0000
19 1.2400 0.0950
20 1.2600 0.0000
21 1.3400 0.0000
22 1.3500 0.0550
23 1.3700 0.0000
24 1.4400 0.0000
25 1.4500 0.0300
26 1.4700 0.0000
27 1.5400 0.0000
28 1.5500 0.0165
29 1.5700 0.0000
30 1.6300 0.0000
31 1.6500 0.0080
32 1.6700 0.0000
33 3.5000 0.0000
34 4.0000 0.0000
35 5.0000 0.0000
36 6.0000 0.0125
37 7.0000 0.0363
38 8.0000 0.0588
39 9.0000 0.0750
40 10.0000 0.0675
41 11.0000 0.0563
42 12.0000 0.0475
43 13.0000 0.0300
44 14.0000 0.0175
45 15.0000 0.0088
46 20.0000 0.0000
47 45.0000 0.0000
48 10000.0000 0.0000
O2 V=4 LINDER AND SCHMIDT X2 WITH 9EV RES FRM WONG-TRAJMAR
ENERGY LOSS = 0.750 , LOWER LIMIT = 0.748 , UPPER LIMIT = 14.990 ,
QSCALE = 1.250000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 0.7500 0.0000
3 0.7900 0.0000
4 0.8000 0.0015
5 0.8200 0.0000
6 0.9000 0.0000
7 0.9100 0.0055
8 0.9300 0.0000
9 1.0200 0.0000
10 1.0300 0.0003
11 1.0500 0.0000
12 1.1300 0.0000
13 1.1400 0.0165
14 1.1600 0.0000
15 1.2300 0.0000
16 1.2400 0.0315
17 1.2600 0.0000
18 1.3400 0.0000
19 1.3500 0.0335
20 1.3700 0.0000
21 1.4400 0.0000
22 1.4500 0.0285
23 1.4700 0.0000
24 1.5400 0.0000
25 1.5500 0.0215
26 1.5700 0.0000
27 1.6300 0.0000
28 1.6500 0.0165
29 1.6700 0.0000
30 6.0000 0.0000
31 7.0000 0.0275
32 8.0000 0.0350
33 9.0000 0.0413
34 10.0000 0.0462
35 11.0000 0.0313
36 12.0000 0.0250
37 13.0000 0.0175
38 14.0000 0.0088
39 15.0000 0.0000
40 10000.0000 0.0000
O2 SING DELTA FROM LINDER-SCHMIDT AND TRAJMAR ET AL
ENERGY LOSS = 0.977 , LOWER LIMIT = 0.929 , UPPER LIMIT = 100.001 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 0.9770 0.0000
3 1.5000 0.0058
4 2.0000 0.0153
5 3.0000 0.0380
6 3.5000 0.0490
7 4.0000 0.0570
8 5.0000 0.0740
9 5.6200 0.0825
10 5.9100 0.0862
11 6.1900 0.0888
12 6.5300 0.0908
13 6.9900 0.0914
14 7.6100 0.0891
15 7.8900 0.0863
16 8.9600 0.0768
17 10.0400 0.0679
18 13.0000 0.0527
19 15.1000 0.0455
20 17.5000 0.0387
21 20.5000 0.0324
22 24.9000 0.0256
23 30.9000 0.0196
24 41.0000 0.0137
25 45.0000 0.0120
26 10000.0000 0.0000
O2 B SINGLET SIGMA FROM LINDER-SCHMIDT AND TRAJMAR ET AL
ENERGY LOSS = 1.627 , LOWER LIMIT = 1.496 , UPPER LIMIT = 100.001 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 1.6270 0.0000
3 2.0000 0.0026
4 3.0000 0.0097
5 3.5000 0.0133
6 4.0000 0.0149
7 5.0000 0.0182
8 5.6900 0.0194
9 6.5400 0.0194
10 7.3400 0.0191
11 8.4100 0.0183
12 9.2600 0.0174
13 10.0000 0.0160
14 13.0000 0.0130
15 14.9000 0.0130
16 17.0000 0.0130
17 19.4000 0.0125
18 20.7000 0.0125
19 22.5000 0.0110
20 24.0000 0.0100
21 28.0000 0.0080
22 35.1000 0.0063
23 41.9000 0.0018
24 45.1000 0.0005
25 1000.0000 0.0000
26 10000.0000 0.0000
O2 V=1 9V RES OF WONG ET AL NORM TO TRAJMAR ET AL
ENERGY LOSS = 0.190 , LOWER LIMIT = 3.999 , UPPER LIMIT = 44.995 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 4.0000 0.0000
3 5.0000 0.0420
4 6.0000 0.1000
5 7.0000 0.1760
6 8.0000 0.2310
7 9.0000 0.2470
8 10.0000 0.2340
9 11.0000 0.1860
10 12.0000 0.1430
11 13.0000 0.1020
12 14.0000 0.0710
13 15.0000 0.0400
14 20.0000 0.0100
15 45.0000 0.0000
16 10000.0000 0.0000
O2 V=2 9V RES OF WONG ET AL NORM TO TRAJMAR ET AL
ENERGY LOSS = 0.380 , LOWER LIMIT = 3.999 , UPPER LIMIT = 44.995 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 4.0000 0.0000
3 5.0000 0.0280
4 6.0000 0.0400
5 7.0000 0.0730
6 8.0000 0.0940
7 9.0000 0.1100
8 10.0000 0.1090
9 11.0000 0.0930
10 12.0000 0.0730
11 13.0000 0.0510
12 14.0000 0.0280
13 15.0000 0.0130
14 20.0000 0.0050
15 45.0000 0.0000
16 10000.0000 0.0000
O2 4.5 LOSS
ENERGY LOSS = 4.500 , LOWER LIMIT = 4.386 , UPPER LIMIT = 14.990 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 4.5000 0.0000
3 4.8000 0.0030
4 5.0000 0.0090
5 5.5000 0.0300
6 6.0000 0.0650
7 6.5000 0.0850
8 7.0000 0.0950
9 7.5000 0.1000
10 8.0000 0.1000
11 9.0000 0.0850
12 10.0000 0.0700
13 12.0000 0.0450
14 15.0000 0.0000
15 50.0000 0.0000
16 10000.0000 0.0000
O2 6.0 LOSS
ENERGY LOSS = 6.000 , LOWER LIMIT = 5.882 , UPPER LIMIT = 100.001 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 6.0000 0.0000
3 7.0000 0.1500
4 7.8000 0.2300
5 9.0000 0.2300
6 10.0000 0.2100
7 12.0000 0.1650
8 15.0000 0.1050
9 17.0000 0.0650
10 20.0000 0.0475
11 45.0000 0.0190
12 10000.0000 0.0000
O2 8.4 LOSS HAYASHI ABOVE 20EV - CHANTRY BELOW
ENERGY LOSS = 8.400 , LOWER LIMIT = 8.282 , UPPER LIMIT = 100.001 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 8.4000 0.0000
3 9.4000 1.0000
4 30.0000 0.9000
5 50.0000 0.7000
6 100.0000 0.5400
7 150.0000 0.3200
8 200.0000 0.2700
9 300.0000 0.1700
10 500.0000 0.1090
11 700.0000 0.0800
12 1000.0000 0.0580
13 1500.0000 0.0420
14 2000.0000 0.0330
15 3000.0000 0.0240
16 5000.0000 0.0160
17 7000.0000 0.0120
18 10000.0000 0.0090
O2 9.97 LOSS TRAJMAR
ENERGY LOSS = 10.000 , LOWER LIMIT = 9.778 , UPPER LIMIT = 100.001 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 10.0000 0.0000
3 20.0000 0.0130
4 30.0000 0.0260
5 40.0000 0.0400
6 50.0000 0.0500
7 60.0000 0.0600
8 70.0000 0.0650
9 80.0000 0.0700
10 100.0000 0.0700
11 120.0000 0.0500
12 150.0000 0.0400
13 170.0000 0.0350
14 200.0000 0.0300
15 300.0000 0.0200
16 500.0000 0.0120
17 700.0000 0.0080
18 1000.0000 0.0050
19 1500.0000 0.0000
20 2000.0000 0.0000
21 3000.0000 0.0000
22 5000.0000 0.0000
23 7000.0000 0.0000
24 10000.0000 0.0000
O2 IONIZATION
ENERGY LOSS = 12.060 , LOWER LIMIT = 11.894 , UPPER LIMIT = 100.001 ,
WEIGHT = 31.740000, EBR= 17.400000, QSCALE= 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 12.0600 0.0000
3 13.0000 0.0230
4 18.0000 0.2000
5 28.0000 0.7400
6 38.0000 1.3200
7 48.0000 1.8000
8 58.0000 2.1000
9 68.0000 2.3300
10 78.0000 2.5000
11 88.0000 2.6000
12 100.0000 2.7000
13 150.0000 2.7000
14 200.0000 2.5000
15 300.0000 2.1700
16 500.0000 1.6600
17 700.0000 1.3500
18 1000.0000 1.0400
19 1500.0000 0.7600
20 2000.0000 0.6000
21 3000.0000 0.4200
22 5000.0000 0.2700
23 7000.0000 0.2000
24 10000.0000 0.1400
O2 130 NM LINE MUMMA-ZIPF
ENERGY LOSS = 14.700 , LOWER LIMIT = 14.500 , UPPER LIMIT = 100.001 ,
QSCALE = 1.000000
ENERGY CROSS SECTION
1 0.0000 0.0000
2 14.7000 0.0000
3 20.0000 0.0085
4 25.0000 0.0160
5 30.0000 0.0225
6 40.0000 0.0280
7 60.0000 0.0370
8 70.0000 0.0380
9 80.0000 0.0390
10 100.0000 0.0380
11 500.0000 0.0000
12 10000.0000 0.0000
THE FOLLOWING IS NOT PART OF THE ABOVE 1978 SET OF CROSS SECTIONS:
O2 DISSOCIATION - BASED ON TABLE I OF
P. C. Cosby, J. Chem. Phys. 98, 9560 (1993).
For use in BACKPRO one would need to extend this to the maximum energy of
the calculation. I haven't looked to see what would make the best cross
section to use as a guide - probably the 9.97 eV loss cross section.
ENERGY CROSS SECTION
0 0
8 0
13.5 0.22
18.5 0.53
21 0.56
23.5 0.52
28.5 0.59
33.5 0.66
38.5 0.61
48.5 0.53
58.5 0.44
73.5 0.37
98.5 0.33
148.5 0.30
198.5 0.29
A rough estimate of the dissociation of O2 by electrons at
high energies is to use the cross section and rate coefficient
for the "O2 8.4 LOSS" process given in the above tabe. This
approximation will considerably over estimate the dissociation
according to Cosby at below 30 eV and most usual E/n. The
similarity to the estimated Schuman-Runge excitation in the
1978 set is not surprising, but the discrepancy at energies
below 30 eV is very bothersome.
A way to calculate the rate coefficients for dissociation of O2
by electrons is to use the "O2 DISSOCIATION" cross section
listed above by first multiplying it by, for example, 1E-4;
using BACKPRO or equivalent to calculate rate coefficients for
the combined set of cross sections; and multiplying the rate
coefficient for dissociation by 1E4. This procedure preserves
the energy balance, transport coefficients, and ionization
coefficients of the 1978 set.
ELECTRON ATTACHMENT TO EXCITED O2
These notes were assembled in response to an inquiry as to the
data available data on electron attachment to excited O2.
1) The dissociative attachment cross section for
O2a-state appears to have been measured most recently
by Jaffke, Meinke, Hashemi, Christophorou, and
Illenberger, Chem. Phys. Lett. 193, 62 (1992). The
cross section is roughly a Gaussian with a peak
magnitude of 5.7E-18 cm^2 at 5.3 eV. Other
measurements give significantly lower peak cross
sections of 4.6+-1.3E-18 (Burrow, 1973) and
3.8+-1.2E-18 cm^2 (Belic and Hall, 1981). Note that if
the Belic and Hall value for the fractional excitation
of the O2a-state were high, e.g., if they missed gas
density reduction because of possible gas heating and
flow effects, their cross section would be low. I
suggest using a peak value of 5E-18 cm^2.
Note that some of the experiments show a second peak in
the dissociative attachment cross section from the
O2a-state. It peaks at 7.5 eV and has a magnitude of
1.7E-18 cm^2.
A very rough estimate of the effects of including
dissociative attachment to the O2a-state is a factor of
two increase in the rate of O formation at typical
discharge electron average energies. The rate
coefficient for this process would decrease as the
average electron energy is decreased.
2) One should also consider dissociative attachment
from the b-state. Unfortunately there appear to be no
cross sections. I would expect the cross section to be
roughly a Gaussian shifted down in energy from that of
the O2a-state dissociative attachment curve by about
the difference in the O2a- and O2b-state thresholds of
0.65 eV. It should be larger in magnitude by a
significant factor because of a higher survival factor.
I would suggest a peak magnitude of 10E-17 cm^2, which
is close to the maximum allowed for a peak of
reasonable energy width. Apparently, the dissociative
process is expected to have a second peak at about 6.9
eV. I would guess this peak to be roughly 5E-18 cm^2.
Overall these processes mean perhaps a factor of 1.5
increase in O formation at high O2b-state
concentration. Again, the rate coefficient for this
process would decrease as the average electron energyHas
is decreased.
3) Dissociative attachment to vibrationally excited O2
has been measured, but probably theory is more useful.
See O'Malley, Phys. Rev. 155, 59 (1967). Because of
the fast relaxation of vibrationally excited O2 by O,
this may not increase the O- formation significantly.
4) Three-body attachment of electrons to the O2a-state
molecules has been predicted theoretically to be as
much as 1000 times smaller than that for O2X-state
molecules. See Aleksandrov, Chem. Phys. Lett. 212, 409
(1993). This will result in a some decrease in the
calculated overall three-body attachment rate
coefficient when the O2a-state fraction becomes
significant.
REVISION OF TOTAL AND PARTIAL IONIZATION CROSS SECTIONS:
See Straub et al, Phys. Rev. A 54, 2146 (1996) and
Stebbings and Lindsay, J. Chem. Phys. 114, 4741 (2001).
RECENT DEVELOPMENTS:
Stephen Biagi at sfb@hep.ph.liv.ac.uk has derived a set of
electron-O2 cross sections that differ somewhat from the
above set. I still prefer the low energy cross sections
given above. However, the available experimental and
theoretical data does not provide definitive values.
Communicated January 2002
Latest O2 changes 12/18/03
***************************************************************
NITROGEN - N2 - 1985 SET OF PHELPS AND PITCHFORD
These cross sections are those used in Phelps and
Pitchford, Phys. Rev. 31, 2932 (1985). The values tabulated
in JILA Information Center Report No. 26 are from the same
computer files. Since this report was issued, we have
recommended that the values listed in the report for the
C^3Pi_u excitation cross section with a threshold at 11.03 eV
be multiplied by 0.67. See footnote 15 of Jelenkovic and
Phelps, Phys. Rev. 36, 5310 (1987). A few errors in Report
No. 26 pointed out by M. Hayashi have been corrected, i.e.,
entry 21 for the 11.03 eV loss and entry 3 for the 11.88 eV
loss. Here the ionization cross section of Report 26 has
been divided into two parts so as to facilitate calculation
of the production N2 1st Negative band emission.
For each of the electronic excitation cross sections in this 1985
set one can recover the cross section obtained by Phelps and
Pitchford from analyses of electron beam experiments and theory.
To do this simply divide the tabulated cross sections by the
quantity QSCALE listed at the head of the table for that process.
The QSCALE factors in this file are given only so that one can
recover the input data to BACKPRO, e.g., the input data used by
P&P (1985). These QSCALE values should NOT be used when the
tabulated data is used as input for BACKPRO, i.e., use QSCALE=1.
For N2 these input data were either Schulz’s published vibrational
excitation cross sections with modification near threshold or
the electronic excitation cross sections derived by P&P (1985)
from the literature. The tabulated numbers in Report 26 and
ELECTRON.TXT (this file) are the result of applying the QSCALE
factors to the input. These tabulated values (except for
C^3Pi_u - see above) were used in the Boltzmann calculations