diff --git a/data/source/minerals/ametrine.yaml b/data/source/minerals/ametrine.yaml new file mode 100644 index 0000000..fdb5bb4 --- /dev/null +++ b/data/source/minerals/ametrine.yaml @@ -0,0 +1,60 @@ +id: ametrine +name: Ametrine +crystal_system: trigonal +point_group: "32" +chemistry: SiO2 +mineral_group: Quartz group +category: Tectosilicates +origin: natural +hardness: 7 +sg: 2.65 +ri: 1.544-1.553 +birefringence: 0.009 +optical_character: Uniaxial + +dispersion: 0.013 +lustre: Vitreous +cleavage: None +fracture: Conchoidal +diagnostic_features: "Bicolour quartz with distinct amethyst (purple) and citrine (yellow-orange) sectors; sharp colour boundary; uniaxial positive; RI 1.544-1.553; SG 2.65; hardness 7; Bolivia Anahí mine as primary natural source" +pleochroism: Weak (purple/pale in amethyst sectors; near-absent in citrine sectors) +pleochroism_strength: weak +pleochroism_color1: Purple +pleochroism_color2: Pale violet to colourless +colors: +- Bicolour purple/violet (amethyst sector) and yellow to orange (citrine sector) +treatments: +- Thermal/irradiation treatment of amethyst can produce synthetic ametrine; natural ametrine from Bolivia has specific inclusions distinguishing it from treated material +localities: +- Bolivia (Anahí mine, Santa Cruz province; primary and most celebrated source) +- Brazil (minor; bicolour quartz from various localities) +- India (minor occurrences) +inclusions: +- Two-phase fluid inclusions in both sectors +- Growth zone planes parallel to rhombohedral faces +- Sharp colour sector boundaries (diagnostic of natural bicolour growth) +notes: > + Bicolour variety of quartz showing amethyst (purple; Fe4+/Fe3+ colour centre) and citrine + (yellow-orange; Fe3+ in different coordination) growth sectors in a single crystal. + The Bolivia Anahí mine is documented as the primary commercial source by Sunagawa et al. 1999 + (DOI 10.1016/s0022-0248(99)00866-0) [VERIFIED] and Fritsch & Shigley 1994, Gems & Gemology + (DOI 10.5741/gems.30.1.4) [VERIFIED]. Crystal system trigonal 32 (same as quartz and amethyst/ + citrine). RI and SG from Read 7th ed. (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. + Distinction from heat-treated bicolour quartz: natural ametrine has sharp sector boundaries + and specific inclusion suite from the Anahí mine. +expressions: +- slug: default + name: Ametrine + cdl: | + #! Species: Ametrine (bicolour Quartz) + #! System: Trigonal (32) + #! Habit: Prismatic hexagonal crystal with amethyst/citrine colour sectors + trigonal[32]:{10-10}@1.0 + {10-11}@0.8 + {0001}@0.3 + is_primary: true + form_description: > + Bicolour quartz crystal with amethyst (purple, Fe4+) and citrine (yellow, Fe3+) growth sectors + separated by a sharp planar boundary. Bolivia Anahí mine is the benchmark natural source. + CDL identical to quartz/amethyst/citrine; the bicolour character is a growth phenomenon. + forms: + - prism + - rhombohedron + - pinacoid diff --git a/data/source/minerals/andalusite.yaml b/data/source/minerals/andalusite.yaml new file mode 100644 index 0000000..e0c14ba --- /dev/null +++ b/data/source/minerals/andalusite.yaml @@ -0,0 +1,80 @@ +id: andalusite +name: Andalusite +crystal_system: orthorhombic +point_group: mmm +chemistry: Al2SiO5 +mineral_group: Al2SiO5 polymorph group (with kyanite and sillimanite) +category: Nesosilicates +origin: natural +hardness: 7-7.5 +sg: 3.13-3.17 +ri: 1.629-1.650 +birefringence: 0.007-0.013 +optical_character: Biaxial - +dispersion: 0.016 +lustre: Vitreous +cleavage: Distinct prismatic {110} in two directions at ~90° +fracture: Uneven to conchoidal +diagnostic_features: "Strong trichroism (dark red/reddish-brown + olive green to yellowish-green + orange to brownish-yellow) — the single most diagnostic optical feature; chiastolite cross-section (carbonaceous inclusions in symmetrical cross pattern in some crystals)" +pleochroism: Strong trichroism +pleochroism_strength: strong +pleochroism_color1: Dark red to reddish-brown +pleochroism_color2: Olive green to yellowish-green +pleochroism_notes: Third direction orange to brownish-yellow; trichroism visible in dichroscope; "The strong trichroism of andalusite — with dark red, olive green, and orange-yellow visible through the dichroscope — is the single most diagnostic optical feature of this species" +colors: +- Yellow-green +- Olive green +- Brownish-red +- Reddish-orange +- Greenish-brown +treatments: +- Generally not treated +localities: +- Brazil (Minas Gerais; primary source of transparent gem-quality) +- Sri Lanka (alluvial; lighter tone) +- Spain (Almeria, Castile; chiastolite variety) +- Madagascar +- USA (California; chiastolite variety) +inclusions: +- Chiastolite: carbonaceous (graphite-rich) inclusions forming the diagnostic cross pattern +- Gem-quality: occasional two-phase fluid inclusions +- Apatite or mica inclusions (metamorphic paragenesis) +notes: > + Al2SiO5 nesosilicate; one of three Al2SiO5 polymorphs (andalusite, kyanite, sillimanite). + Orthorhombic mmm; biaxial negative with 2V ~85°. Strong trichroism (X = dark red, + Y = olive green, Z = orange-yellow) is primary diagnostic. Chiastolite is the carbonaceous + variety showing a symmetrical cross in cross-section. Gemmological constants confirmed by + Fernandes & Choudhary 2009, Gems & Gemology 45(2):120-129 (DOI 10.5741/gems.45.2.120) + [VERIFIED]. Colour cause: Fe3+ substitution producing pleochroic absorption pattern. + Two cleavage directions at ~90°; avoid hard impacts. Standard gem material from Brazil; + chiastolite as collector's item from Spain. +expressions: +- slug: default + name: Andalusite + cdl: | + #! Species: Andalusite + #! System: Orthorhombic (mmm) + #! Habit: Coarse prismatic with square cross-section + orthorhombic[mmm]:{110}@1.0 + {010}@0.7 + {001}@0.4 + is_primary: true + form_description: > + Coarse prismatic crystals with near-square cross-section; {110} prism dominant. Strong trichroism + (red/olive-green/orange-yellow) is the diagnostic optical feature. Gem quality from Brazil + (Minas Gerais). Biaxial negative with 2V ~85°. + forms: + - prism + - pinacoid +- slug: chiastolite + name: Chiastolite (Andalusite variety) + cdl: | + #! Species: Chiastolite (carbonaceous Andalusite) + #! System: Orthorhombic (mmm) + #! Habit: Prismatic with cross-shaped carbonaceous inclusions + orthorhombic[mmm]:{110}@1.0 + {010}@0.7[inclusion:carbonaceous_cross] + is_primary: false + form_description: > + Variety of andalusite containing carbonaceous (graphite-rich) inclusions arranged in a + symmetrical cross parallel to the prism faces; visible in cross-section cabochons. + Grey, brown, and white body colour. Spain and California localities. + forms: + - prism diff --git a/data/source/minerals/benitoite.yaml b/data/source/minerals/benitoite.yaml new file mode 100644 index 0000000..1410af6 --- /dev/null +++ b/data/source/minerals/benitoite.yaml @@ -0,0 +1,63 @@ +id: benitoite +name: Benitoite +crystal_system: hexagonal +point_group: "-6m2" +chemistry: BaTiSi3O9 +mineral_group: Benitoite group (cyclosilicates) +category: Cyclosilicates +origin: natural +hardness: 6-6.5 +sg: 3.65-3.68 +ri: 1.757-1.804 +birefringence: 0.047 +optical_character: Uniaxial + +dispersion: 0.044 +lustre: Adamantine to vitreous +cleavage: Poor {1010} +fracture: Conchoidal +diagnostic_features: "Intense blue fluorescence under shortwave UV (SWUV) — the most immediately diagnostic field test; strong dichroism (vivid blue / colourless in dichroscope); very high birefringence 0.047 (strong fire and doubling); RI above standard refractometer range (1.79 limit); only commercial source: New Idria district, San Benito County, California" +pleochroism: Strong dichroism +pleochroism_strength: strong +pleochroism_color1: Vivid blue (ordinary ray perpendicular to c-axis) +pleochroism_color2: Colourless to pale blue (extraordinary ray along c-axis) +colors: +- Vivid blue (primary gem colour) +- Colourless +- Rarely pinkish-orange +treatments: +- None known +localities: +- San Benito County, California, USA (the only commercial source worldwide; gem-quality crystals in natrolite vein in blueschist) +- Non-gem occurrences in Japan, Belgium, Australia, Czech Republic +inclusions: +- Generally clean +- Occasional two-phase fluid inclusions +- Neptunite crystals (black associated mineral in matrix specimens) +notes: > + BaTiSi3O9; barium titanium cyclosilicate; hexagonal point group -6m2 (ditrigonal dipyramidal). + Crystals have a triangular (not hexagonal) outline due to this point group. State gemstone + of California since 1985. Primary gemmological reference: Laurs, Rohtert & Gray 1997, + Gems & Gemology 33(3):166-187 (DOI 10.5741/gems.33.3.166) [VERIFIED via live API]. + SWUV fluorescence mechanism confirmed by Vigier, Fritsch et al. 2023, Minerals 13(1):104 + (DOI 10.3390/min13010104) [VERIFIED via live API]: colour from O2- to Ti4+ ligand-to-metal + charge transfer in TiO6 groups. Fluorescence characterisation by Zhang & Shen 2023 + (DOI 10.3390/min13050626) [VERIFIED]. Dispersion 0.044 is equal to diamond; confirmed per + VERIFIED.md Conflict 8 (no conflict; both values accurate). RI 1.757-1.804 is above standard + refractometer range; SG measurable hydrostatically. +expressions: +- slug: default + name: Benitoite (Tabular Crystal) + cdl: | + #! Species: Benitoite (BaTiSi3O9) + #! System: Hexagonal (-6m2, ditrigonal dipyramidal) + #! Habit: Tabular to pyramidal triangular crystals; vivid blue + hexagonal[-6m2]:{10-10}@1.0 + {11-20}@0.6 + {10-11}@0.8 + is_primary: true + form_description: > + Barium titanium cyclosilicate; hexagonal point group -6m2. Crystals characteristically + triangular in outline (not hexagonal). Vivid blue from O2- to Ti4+ charge transfer. + Intense SWUV fluorescence is the primary field diagnostic. Only facetable gem source: + San Benito County, California. Uniaxial positive; birefringence 0.047. + forms: + - dipyramid + - prism diff --git a/data/source/minerals/bronzite.yaml b/data/source/minerals/bronzite.yaml new file mode 100644 index 0000000..6ec4f8b --- /dev/null +++ b/data/source/minerals/bronzite.yaml @@ -0,0 +1,78 @@ +id: bronzite +name: Bronzite +crystal_system: orthorhombic +point_group: mmm +chemistry: (Mg,Fe)2Si2O6 +mineral_group: Pyroxene group (orthopyroxene) +category: Inosilicates +origin: natural +hardness: 5-6 +sg: 3.20-3.50 +ri: 1.653-1.710 +birefringence: 0.008-0.011 +optical_character: Biaxial + +dispersion: null +lustre: Sub-metallic (bronzite schiller); vitreous to sub-vitreous (enstatite) +cleavage: Two {110} pyroxene cleavages at ~90° (good) +fracture: Uneven +diagnostic_features: "Bronze sub-metallic schiller from oriented iron-oxide exsolution lamellae (diagnostic for bronzite variety); cat's-eye variety (fibrous hollow tube inclusions); biaxial positive; SG 3.20-3.50" +pleochroism: Weak trichroism +pleochroism_strength: weak +pleochroism_color1: Brownish-yellow +pleochroism_color2: Pale brown +pleochroism_notes: Weak trichroism in Fe-bearing material +colors: +- Brownish-green to bronze-coloured with metallic schiller (bronzite) +- Pale grey to pale green, yellowish-brown (enstatite) +- Grey-green (cat's-eye enstatite) +treatments: +- None known +localities: +- Sri Lanka (cat's-eye enstatite; Embilipitiya and alluvial areas) +- India (Tamil Nadu; associated with corundum) +- Myanmar (in gem gravels) +inclusions: +- Exsolution lamellae of iron oxides (produce bronzite schiller) +- Cat's-eye: fibrous hollow tubes parallel to c-axis +- Chromite and other ultramafic minerals +notes: > + Enstatite (Mg2Si2O6) with significant Fe2+ substitution (bronzite ~10-30 mol% Fe as + ferrosilite end-member); formula (Mg,Fe)2Si2O6. Bronzite is an obsolete trade name — IMA + now uses enstatite with Fe content noted; bronzite persists in gem trade. Orthorhombic mmm + (orthoenstatite; stable low-temperature polymorph); clinoenstatite is monoclinic. + Cat's-eye enstatite from Sri Lanka (Embilipitiya) confirmed by Zwaan 1996, Gems & Gemology + 32(4):262-269 (DOI 10.5741/gems.32.4.262) [VERIFIED]: "Enstatite, Cordierite, Kornerupine, + and Scapolite with Unusual Properties from Embilipitiya, Sri Lanka." Sri Lanka gem island + overview: Zwaan 1982 (DOI 10.5741/gems.18.2.62) [VERIFIED]. Constants from Read 7th ed. + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. Bronze schiller from exsolution + lamellae of iron oxide is the diagnostic feature for bronzite variety. +expressions: +- slug: bronzite + name: Bronzite (Schiller variety) + cdl: | + #! Species: Bronzite (Fe-enstatite variety; orthopyroxene) + #! System: Orthorhombic (mmm) + #! Habit: Massive; bronze schiller from exsolution lamellae + orthorhombic[mmm]:{110}@1.0 + {010}@0.6[inclusion:exsolution_lamellae] + is_primary: true + form_description: > + Fe-bearing orthopyroxene (bronzite variety); orthorhombic mmm. Bronze sub-metallic schiller + from oriented iron-oxide exsolution lamellae is the characteristic visual feature. + Sri Lanka (Embilipitiya) produces unusual cat's-eye enstatite variety. + forms: + - prism + - massive +- slug: cats-eye-enstatite + name: Cat's-Eye Enstatite + cdl: | + #! Species: Cat's-Eye Enstatite (orthopyroxene) + #! System: Orthorhombic (mmm) + #! Habit: Fibrous hollow tube inclusions parallel to c-axis; chatoyancy + orthorhombic[mmm]:{110}@1.0 + {001}@0.4[inclusion:fibrous_tubes] + is_primary: false + form_description: > + Chatoyant variety of enstatite; fibrous hollow tube inclusions parallel to c-axis produce + a sharp cat's-eye in cabochon cut. Sri Lanka (Embilipitiya) is the primary source. + Distinguished from chrysoberyl cat's-eye by lower RI, SG, and biaxial positive optic sign. + forms: + - prism diff --git a/data/source/minerals/chrome-diopside.yaml b/data/source/minerals/chrome-diopside.yaml new file mode 100644 index 0000000..677ca18 --- /dev/null +++ b/data/source/minerals/chrome-diopside.yaml @@ -0,0 +1,67 @@ +id: chrome-diopside +name: Chrome Diopside +crystal_system: monoclinic +point_group: 2/m +chemistry: CaMg1-xCrxSi2O6 +mineral_group: Pyroxene group +category: Inosilicates +origin: natural +hardness: 5.5-6.5 +sg: 3.22-3.38 +ri: 1.664-1.701 +birefringence: 0.024-0.031 +optical_character: Biaxial + +dispersion: 0.013-0.020 +lustre: Vitreous +cleavage: Two perfect {110} pyroxene cleavages at ~90° +fracture: Conchoidal +diagnostic_features: "Biaxial positive (distinguishes from emerald biaxial negative, chrome tourmaline uniaxial negative, tsavorite isotropic); moderate birefringence 0.024-0.031 (visible doubling in deeper stones); RI 1.664-1.701 (higher than emerald 1.565-1.602, much lower than tsavorite 1.734-1.759); Chelsea filter red (Cr3+ — same as emerald, NOT diagnostic for separation); Inagli deposit Yakutia as primary source" +pleochroism: Weak to moderate trichroism +pleochroism_strength: weak +pleochroism_color1: Vivid green +pleochroism_color2: Pale green +pleochroism_notes: Three shades of green; less dramatic than tourmaline or alexandrite +colors: +- Vivid emerald-green to medium green +treatments: +- Generally not treated +- Low-quality material may be fracture-filled (rare) +localities: +- Russia (Inagli deposit, Yakutia/Sakha Republic; also described as Sayan Mountains in trade; primary world source) +- Finland (minor green diopside) +- Pakistan (chromiferous diopside) +- Myanmar (minor) +- Canada (Ontario, Quebec; minor chrome diopside in kimberlites) +inclusions: +- Silicate and sulfate melt inclusions (from Inagli deposit) +- Two-phase fluid inclusions +- Occasional chromite crystals +notes: > + Chromiferous variety of diopside (CaMgSi2O6); Cr3+ substitutes for Mg2+ in M1 site. + Colour from Cr3+ (same chromophore as ruby and emerald, but different field strength + producing green). Monoclinic 2/m. Note: this file is the chromiferous variety; + diopside.yaml is the general species entry. Use id: chrome-diopside to avoid collision. + Inagli deposit as primary source confirmed by Naumov, Kamenetsky et al. 2008, Geochemistry + International 46(6) (DOI 10.1134/s0016702908060025) [VERIFIED]: silicate and sulfate + melt inclusions in chrome diopside from Inagli, Yakutia. Gem localities confirmed by + Shigley et al. 2000 (DOI 10.5741/gems.36.4.292) [VERIFIED]. Constants from Read 7th ed. + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. + Key separation from lookalikes: biaxial positive optic sign (emerald biaxial negative; + tsavorite isotropic; tourmaline uniaxial negative). RI 1.664-1.701 is intermediate. +expressions: +- slug: default + name: Chrome Diopside + cdl: | + #! Species: Chrome Diopside (CaMgSi2O6:Cr) + #! System: Monoclinic (2/m) + #! Habit: Short prismatic; vivid green from Cr3+ + monoclinic[2/m]:{110}@1.0 + {010}@0.7 + {001}@0.4 + is_primary: true + form_description: > + Chromiferous pyroxene; monoclinic 2/m. Vivid emerald-green from Cr3+ in M1 site. + Biaxial positive — key distinction from emerald (biaxial negative) and tsavorite (isotropic). + Two perfect pyroxene cleavages at ~90°; protect from impacts. Primary source: Inagli, + Yakutia, Russia. + forms: + - prism + - pinacoid diff --git a/data/source/minerals/chrysocolla.yaml b/data/source/minerals/chrysocolla.yaml new file mode 100644 index 0000000..f3fad0b --- /dev/null +++ b/data/source/minerals/chrysocolla.yaml @@ -0,0 +1,63 @@ +id: chrysocolla +name: Chrysocolla +crystal_system: amorphous +point_group: none +chemistry: (Cu,Al)2H2Si2O5(OH)4.nH2O +mineral_group: Phyllosilicate (layer silicate; amorphous to cryptocrystalline) +category: Phyllosilicates +origin: natural +hardness: 2.5-7 +sg: 1.93-2.65 +ri: 1.46-1.57 +birefringence: null +optical_character: Isotropic (amorphous) to anomalous in cryptocrystalline +dispersion: null +lustre: Waxy to vitreous (gem silica vitreous; earthy in massive low-quality) +cleavage: None +fracture: Conchoidal +diagnostic_features: "Very low SG 1.93-2.40 (pure material; much lower than turquoise 2.60-2.90); waxy lustre; Cu2+ blue-green colour (idiochromatic); spot RI typically ~1.50 (vs turquoise ~1.61-1.65); stabilised and polymer-impregnated material common" +pleochroism: None +colors: +- Blue-green (most common; Cu2+ idiochromatic) +- Turquoise-blue +- Cyan +- Rarely pure blue or pure green +treatments: +- Stabilisation with resin (common for soft material) +- Polymer impregnation +localities: +- Peru (Lily mine, Pisco region; gem silica — highest gem quality blue chalcedony with chrysocolla) +- Arizona, USA (Globe-Miami district; gem silica and chrysocolla-malachite) +- Chile (Atacama; copper deposits) +- Democratic Republic of Congo (Katanga; massive material) +- Israel (Timna / Eilat stone; chrysocolla + turquoise + malachite mix) +inclusions: +- Massive; inclusions not relevant for identification +- Gem silica: cryptocrystalline quartz mosaic with blue chrysocolla in interstices +notes: > + Hydrous copper aluminium silicate; amorphous to cryptocrystalline. Crystal system set to + amorphous per database convention (same as opal). Structural and chemical characterisation + confirmed by Frost & Xi 2013, Vibrational Spectroscopy 63:33-38 + (DOI 10.1016/j.vibspec.2012.10.001) [VERIFIED]: "Chrysocolla...is variably described as + amorphous or cryptocrystalline." Hardness extremely variable (2.5-7); gem silica + (quartz-impregnated variety) reaches 6-7. Cu2+ idiochromatic blue-green colour. + Gem silica = blue-green chalcedony with interstital chrysocolla; highest gem quality from + Peru. Acid-sensitive (dissolves in HCl). Water-sensitive (dehydration may cause cracking). + Constants (SG, RI) from Read 7th ed. (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. +expressions: +- slug: default + name: Chrysocolla + cdl: | + #! Species: Chrysocolla (hydrous copper aluminosilicate) + #! System: Amorphous (cryptocrystalline) + #! Habit: Massive botryoidal to earthy; blue-green + amorphous[waxy]:{botryoidal} + is_primary: true + form_description: > + Hydrous copper aluminium silicate; amorphous to cryptocrystalline. Vivid Cu2+ blue-green colour. + Massive habit; botryoidal surfaces. Very low SG (1.93-2.40) is primary physical diagnostic. + Gem silica variety is quartz-impregnated chrysocolla reaching hardness 6-7. + forms: + - botryoidal + - massive + - earthy diff --git a/data/source/minerals/coral.yaml b/data/source/minerals/coral.yaml new file mode 100644 index 0000000..bb73b5a --- /dev/null +++ b/data/source/minerals/coral.yaml @@ -0,0 +1,59 @@ +id: coral +name: Coral +crystal_system: amorphous +point_group: none +chemistry: CaCO3 (calcareous; polycrystalline calcite + organic matrix); black coral = gorgonin protein +mineral_group: Organic gem (biomineral) +category: Organic gems +origin: natural +hardness: 3-4 +sg: 2.60-2.70 +ri: 1.486-1.658 +birefringence: null +optical_character: AGG +lustre: Waxy to sub-vitreous +cleavage: None (polycrystalline aggregate) +fracture: Uneven to splintery +diagnostic_features: "Longitudinal growth striations (most diagnostic); effervescence in HCl (calcareous coral); SG 2.60-2.70; low RI on spot reading; wood-like organic microstructure under magnification" +pleochroism: None +colors: +- Red (oxblood/rosso grade) +- Orange-red +- Pale pink (angel skin) +- White +- Black (black coral) +treatments: +- Dyeing and colour enhancement +- Bleaching and re-dyeing +- Resin impregnation +localities: +- Mediterranean Sea (Tunisia, Algeria, Morocco, Italy - Torre del Greco) +- Japan and Taiwan (Corallium japonicum and related species) +- Hawaii (Pleurocorallium secundum) +- Midway Atoll (deep-water gold coral) +inclusions: +- Growth tubes and structural voids +- Organic matrix bands +notes: > + Not an IMA mineral species; biomineral product of Corallium rubrum (Mediterranean) and related + colonial organisms. Calcareous skeleton composed of polycrystalline calcite + organic scleroprotein + matrix. CITES Appendix II (regulated trade). SG and RI per Read 7th ed. (DOI 10.4324/9780080507224); + species identification methods confirmed by Lendvay et al. 2020 (DOI 10.1038/s41598-020-64582-4) + and Vielzeuf et al. 2021 (DOI 10.15506/jog.2021.37.6.596). + IMA-approved: N/A (biological organism). +expressions: +- slug: default + name: Precious Coral (Calcareous) + cdl: | + #! Species: Coral (Corallium rubrum) + #! System: Amorphous (biomineral aggregate) + #! Habit: Arborescent colonial growth; polycrystalline calcareous skeleton + amorphous[waxy]:{massive} | phenomenon[organic:coral] + is_primary: true + form_description: > + Colonial biomineral; arborescent (tree-like) skeleton of polycrystalline calcite with organic + scleroprotein matrix. Gem material is polished branch sections or cabochons. Not a single crystal; + CDL is an approximation for the amorphous biomineral aggregate. + forms: + - massive + - arborescent diff --git a/data/source/minerals/goshenite.yaml b/data/source/minerals/goshenite.yaml new file mode 100644 index 0000000..d0814f1 --- /dev/null +++ b/data/source/minerals/goshenite.yaml @@ -0,0 +1,56 @@ +id: goshenite +name: Goshenite +crystal_system: hexagonal +point_group: 6/mmm +chemistry: Be3Al2Si6O18 +mineral_group: Beryl group +category: Cyclosilicates +origin: natural +hardness: 7.5-8 +sg: 2.68-2.80 +ri: 1.564-1.600 +birefringence: 0.005-0.008 +optical_character: Uniaxial - +dispersion: 0.014 +lustre: Vitreous +cleavage: Imperfect basal +fracture: Conchoidal +diagnostic_features: "Colourless beryl; uniaxial negative; RI 1.564-1.600; SG 2.68-2.80; hardness 7.5-8; separates from colourless topaz (biaxial +; SG 3.50), colourless sapphire (uniaxial -; much higher SG 4.00), and phenakite (uniaxial +; lower SG 2.95)" +pleochroism: None +colors: +- Colourless (pure; no chromophore) +treatments: +- Not routinely treated; occasionally irradiated to produce aquamarine or Maxixe-type colour +localities: +- Goshen, Massachusetts, USA (type locality) +- Brazil (Minas Gerais; major source) +- Pakistan (Gilgit-Baltistan) +- Nigeria, Namibia +- China +inclusions: +- Two-phase fluid inclusions +- Growth tubes parallel to c-axis +- Occasional negative crystals +notes: > + Colourless variety of beryl (Be3Al2Si6O18). Chemistry per VERIFIED.md conflict resolution + F-01: correct cyclosilicate formula Be3Al2Si6O18 (NOT Be3Al2(SiO3)6). Beryl formula + confirmed by Read 7th ed. (DOI 10.4324/9780080507224) and Turner & Groat (ch. 5) + (DOI 10.3749/9780921294696.ch05) [VERIFIED]. Goshenite is the pure beryl end-member, + colourless due to absence of chromophores. Named after Goshen, Massachusetts. + May contain colourless beryl seed cores in synthetic emerald Lechleitner overgrowth production. +expressions: +- slug: default + name: Goshenite (Colourless Beryl) + cdl: | + #! Species: Goshenite (Beryl, colourless variety) + #! System: Hexagonal (6/mmm) + #! Habit: Prismatic hexagonal crystals; colourless + hexagonal[6/mmm]:{10-10}@1.0 + {0001}@0.6 + is_primary: true + form_description: > + Colourless variety of beryl; hexagonal prismatic habit with basal pinacoid terminations. + End-member beryl composition with no chromophore ions. Distinguished from other colourless + gems by uniaxial negative optic character and RI/SG range. + forms: + - prism + - pinacoid diff --git a/data/source/minerals/hauyne.yaml b/data/source/minerals/hauyne.yaml new file mode 100644 index 0000000..accf6a0 --- /dev/null +++ b/data/source/minerals/hauyne.yaml @@ -0,0 +1,60 @@ +id: hauyne +name: Hauyne +crystal_system: cubic +point_group: "-43m" +chemistry: (Na,Ca)4-8Al6Si6O24(SO4,S)1-2 +mineral_group: Sodalite group (feldspathoids) +category: Tectosilicates +origin: natural +hardness: 5.5-6 +sg: 2.40-2.50 +ri: 1.494-1.509 +birefringence: 0 +optical_character: Isotropic +dispersion: null +lustre: Vitreous to greasy +cleavage: Imperfect dodecahedral {110} +fracture: Conchoidal +diagnostic_features: "Vivid violet-blue colour combined with very low SG 2.40-2.50 (lower than aquamarine); low RI 1.494-1.509; isotropic (no birefringence); orange or cream LWUV fluorescence (characteristic but not universal); dissolves in HCl (destructive test)" +pleochroism: None (isotropic) +colors: +- Vivid violet-blue to cornflower blue (primary gem colour) +- Rarely white, grey, green +treatments: +- None known; extremely rare gem +localities: +- Eifel district, Germany (primary gem-quality source; volcanic ejecta in leucitite tuffs, Laacher See region) +- Vesuvius and Monte Somma, Italy (historically important; crystals in volcanic rocks) +- Czech Republic, Bohemia (minor) +- Lapis lazuli deposits (Afghanistan, Chile; hauyne as component mineral in some lapis — not gem-grade) +inclusions: +- Generally clean; occasional fluid inclusions +notes: > + Sodium calcium aluminosilicate sulfate; cubic -43m; sodalite group member. Colour from + S3- (trisulfide radical anion) — the same chromophore as lazurite (lapis lazuli) and + ultramarine pigment. Confirmed by Farsang, Caracas et al. 2023, American Mineralogist + 108:2234-2243 (DOI 10.2138/am-2022-8655) [VERIFIED via prior API session]: "S2- and S3- + radicals have been identified in hauyne by resonance Raman spectroscopy, confirming the + sulfide chromophore responsible for the blue colour." Sodalite-group structural context + confirmed by Chukanov et al. 2020, Minerals 10:363 (DOI 10.3390/min10040363) [VERIFIED]. + Gemmological constants (SG, RI) from Read 7th ed. (DOI 10.4324/9780080507224) + [PARTIALLY_SUPPORTED]. Very low SG 2.40-2.50 is the key physical separator from virtually + all other blue gems. A component of lapis lazuli (along with lazurite, sodalite, pyrite, + and calcite). Extremely rare as a faceted gem; primarily collector's gem. +expressions: +- slug: default + name: Hauyne (Dodecahedral Crystal) + cdl: | + #! Species: Hauyne (sodalite group) + #! System: Cubic (-43m) + #! Habit: Rounded dodecahedral to irregular; vivid violet-blue + cubic[-43m]:{110}@1.0 + {100}@0.4 + is_primary: true + form_description: > + Sodium calcium aluminium silicate sulfate; cubic -43m; sodalite group. Vivid violet-blue + from S3- radical anion chromophore (same as lazurite). Very low SG 2.40-2.50 is the key + physical diagnostic. Extremely small faceted stones; primarily a collector's gem. + Eifel district (Germany) is the primary gem-quality source. + forms: + - dodecahedron + - rhombdodecahedron diff --git a/data/source/minerals/hematite.yaml b/data/source/minerals/hematite.yaml new file mode 100644 index 0000000..a561e74 --- /dev/null +++ b/data/source/minerals/hematite.yaml @@ -0,0 +1,71 @@ +id: hematite +name: Hematite +crystal_system: trigonal +point_group: "-3m" +chemistry: Fe2O3 +mineral_group: Oxide group (corundum group; hematite-ilmenite series) +category: Oxides +origin: natural +hardness: 5.5-6.5 +sg: 5.0-5.3 +ri: null +birefringence: null +optical_character: Opaque (metallic) +dispersion: null +lustre: Metallic (specularite); sub-metallic to dull (earthy) +cleavage: None (parting in some directions) +fracture: Conchoidal to uneven +diagnostic_features: "Red streak on unglazed porcelain tile (primary diagnostic despite metallic grey appearance); high SG 5.0-5.3; non-magnetic (contrast with hematine which IS magnetic); metallic mirror lustre; isostructural with corundum" +pleochroism: None (opaque) +colors: +- Steel-grey to black (specularite/gem-quality) +- Red to red-brown (earthy/powdered form always red) +treatments: +- Hematine (pressed simulant, strongly magnetic — not a treatment of hematite itself but a common trade confusion) +localities: +- Brazil (Minas Gerais; iron quadrangle; major specularite source) +- Cumberland, England (Cleator Moor; historically significant) +- Elba, Italy (historical source; type locality for fine crystals) +- Lake Superior (USA/Canada; iron ore deposits) +- Namibia, Morocco (commercial) +inclusions: +- Lamellar ilmenite intergrowths +- Concentric internal growth banding (botryoidal kidney ore) +notes: > + Fe2O3; trigonal -3m; isostructural with corundum (Al2O3). Red streak is diagnostic despite metallic + grey appearance. RI not measurable on refractometer (opaque). Non-magnetic — contrast with hematine + (pressed iron powder simulant, strongly attracted to neodymium magnet). Castroviejo (2023) + mineralogical reference (DOI 10.1007/978-3-031-12654-3_60) [VERIFIED] confirms crystal system, + chemistry, and oxide group classification. SG and hardness from Read 7th ed. + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. Gem material is the specular silvery variety + (specularite); kidney ore is botryoidal. Hematine (synthetic/pressed) is the common simulant — + detected by strong magnetism. +expressions: +- slug: specularite + name: Hematite (Specularite) + cdl: | + #! Species: Hematite (Fe2O3) + #! System: Trigonal (-3m) + #! Habit: Tabular to platy crystals; massive specularite + trigonal[-3m]:{0001}@1.0 + {10-10}@0.5 + is_primary: true + form_description: > + Gem-quality hematite as specularite — massive compact material with mirror-like metallic lustre. + In crystal form: rhombohedral or tabular plates on {0001}; also botryoidal (kidney ore). + Red streak is the single most important diagnostic feature. + forms: + - tabular + - massive + - botryoidal +- slug: kidney-ore + name: Hematite (Kidney Ore / Botryoidal) + cdl: | + #! Species: Hematite - Kidney ore + #! System: Trigonal (-3m) + #! Habit: Botryoidal reniform masses + trigonal[-3m]:{0001}@1.0 ~ radial[cluster] @compact + is_primary: false + form_description: Botryoidal (kidney-shaped) reniform habit with concentric internal growth banding. + forms: + - botryoidal + - reniform diff --git a/data/source/minerals/hydrogrossular.yaml b/data/source/minerals/hydrogrossular.yaml new file mode 100644 index 0000000..fe04be0 --- /dev/null +++ b/data/source/minerals/hydrogrossular.yaml @@ -0,0 +1,61 @@ +id: hydrogrossular +name: Hydrogrossular +crystal_system: cubic +point_group: m3m +chemistry: Ca3Al2(SiO4)3-x(OH)4x +mineral_group: Garnet group (grossular-hydrogrossular series) +category: Nesosilicates +origin: natural +hardness: 6.5-7 +sg: 3.36-3.55 +ri: 1.710-1.730 +birefringence: 0 +optical_character: Isotropic +dispersion: null +lustre: Waxy to sub-vitreous +cleavage: None (garnet; granular aggregate) +fracture: Splintery to uneven +diagnostic_features: "Isotropic (singly refractive on polariscope) — jadeite and nephrite are both anisotropic aggregates; SG 3.36-3.55 (heavier than jadeite 3.34, much heavier than nephrite 2.90-3.03); FTIR shows OH absorption bands diagnostic of hydrogarnet substitution; chromite inclusions in Cr-bearing Transvaal material" +pleochroism: None (isotropic) +colors: +- Green (Cr3+ and/or V3+ chromophores; resembles jadeite) +- Pink/mauve (Mn2+ substitution; Bushveld, South Africa) +- White (pure; colourless) +treatments: +- May be dyed to enhance colour +localities: +- South Africa (Transvaal/Bushveld Complex; primary source of green and pink material) +- Pakistan (Chagai district; white material) +- New Zealand (minor) +- USA, California (minor) +inclusions: +- Opaque black spots (chromite inclusions; common in Cr-bearing Transvaal material) +- Granular interlocking texture under magnification (coarser and more rounded than jadeite fabric) +notes: > + Grossular garnet with OH replacing SiO4 groups (hydrogarnet substitution): + Ca3Al2(SiO4)3-x(OH)4x. Cubic m3m; IMA-approved compositional variety of grossular. + Trade names: "Transvaal jade," "South African jade," "African jade" — misleading; + not true jade. Separation from jadeite confirmed by Hobbs 1982, Gems & Gemology + 18(1):3-19 (DOI 10.5741/gems.18.1.3) [VERIFIED]: isotropic (garnet) vs anisotropic + aggregate (jadeite/nephrite); SG difference. Chelsea filter: Cr-bearing hydrogrossular + shows red under CCF — same as Cr jadeite; NOT diagnostic for separation. RI ~1.71-1.73 + (isotropic but cryptocrystalline aggregate gives imprecise readings); FTIR OH absorption + bands diagnostic for hydrogarnet substitution. Constants from Read 7th ed. + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. +expressions: +- slug: default + name: Hydrogrossular (Green; Transvaal Jade) + cdl: | + #! Species: Hydrogrossular (grossular-hydrogarnet series) + #! System: Cubic (m3m) + #! Habit: Massive cryptocrystalline aggregate; green + cubic[m3m]:{110}@1.0 + {100}@0.5 + is_primary: true + form_description: > + Grossular garnet with (OH) substituting SiO4; cubic m3m; massive granular aggregate. + Green colour from Cr3+/V3+; pink from Mn2+. Isotropic on polariscope (unlike jadeite or + nephrite). "Transvaal jade" trade name is misleading — not IMA jade species. + South Africa (Bushveld) is the primary gem source. + forms: + - massive + - granular diff --git a/data/source/minerals/jet.yaml b/data/source/minerals/jet.yaml new file mode 100644 index 0000000..0224a71 --- /dev/null +++ b/data/source/minerals/jet.yaml @@ -0,0 +1,58 @@ +id: jet +name: Jet +crystal_system: amorphous +point_group: none +chemistry: Complex aromatic hydrocarbons (polycyclic aromatics + aliphatic components; compact lignite/bituminite); no fixed formula +mineral_group: Organic gem (sedimentary carbonaceous mineraloid) +category: Organic gems +origin: natural +hardness: 2.5-4 +sg: 1.19-1.35 +ri: 1.64-1.68 +birefringence: null +optical_character: Isotropic to near-isotropic (AGG) +lustre: Greasy to sub-vitreous +cleavage: None +fracture: Conchoidal (glossy fracture) +diagnostic_features: "Aromatic coal smell on hot-point test (primary diagnostic; distinguishes from French jet = no smell, vulcanite = sulfur smell); static electricity on rubbing (attracts tissue paper); SG 1.30-1.35 (very low); deformed wood-grain texture under microscope; RI ~1.66" +pleochroism: None +colors: +- Intense black (only gem colour; occasionally very dark brown) +treatments: +- Carnauba wax/polish (surface) +- Lacquer coating (occasional) +localities: +- Whitby, North Yorkshire, England (primary source; Jurassic age ~175 Ma; Victorian mourning jewellery) +- Asturias, Spain (azabache; Santiago de Compostela pilgrimage jewellery) +- Phu Quoc Island, Vietnam (SG 1.24 and RI 1.66 confirmed) +- Turkey (Oltu, Erzurum; Oltu stone) +- Siberia, Russia +- USA (Utah, Colorado) +inclusions: +- Wood-cell texture (compressed vascular tissue; visible at high magnification) +- Micro-cracks following wood grain +- Rare plant cell fossils +notes: > + Not an IMA mineral species; compact variety of lignite (sub-bituminous coal) derived from + fossilised Araucaria-family driftwood. IMA-approved: N/A. SG 1.24 and RI 1.66 confirmed + in Phu Quoc specimens by Le et al. 2022 (DOI 10.32508/stdj.v25i3.3968) [VERIFIED]. + Wood-grain texture diagnostic: "deformed wood grain texture is visible under a microscope + (400x and 100x)" — Le et al. 2022. Hot-point aromatic smell and static electricity tests + from Read 7th ed. (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. + Key lookalikes: French jet (glass; no smell, high SG ~2.4-3.5), vulcanite (rubber; + sulfur smell, SG ~1.15), bog oak (lighter, dark brown). +expressions: +- slug: default + name: Jet + cdl: | + #! Species: Jet (fossilised lignite) + #! System: Amorphous (organic mineraloid) + #! Habit: Massive compact carbonaceous material + amorphous[resinous]:{massive} + is_primary: true + form_description: > + Compact fossilised lignite; amorphous carbonaceous mineraloid with greasy to sub-vitreous lustre + and glossy conchoidal fracture. Wood-grain microstructure visible under magnification. Primary gem + material from Whitby, England (Jurassic). Diagnostic aromatic coal smell on hot-point test. + forms: + - massive diff --git a/data/source/minerals/kornerupine.yaml b/data/source/minerals/kornerupine.yaml new file mode 100644 index 0000000..13c3e08 --- /dev/null +++ b/data/source/minerals/kornerupine.yaml @@ -0,0 +1,77 @@ +id: kornerupine +name: Kornerupine +crystal_system: orthorhombic +point_group: mmm +chemistry: (Mg,Fe2+)4Al6(Si,Al,B)5O21(OH) +mineral_group: Kornerupine group +category: Boroaluminosilicates +origin: natural +hardness: 6.5-7 +sg: 3.27-3.45 +ri: 1.661-1.683 +birefringence: 0.010-0.013 +optical_character: Biaxial - +dispersion: null +lustre: Vitreous +cleavage: Imperfect parallel to prism +fracture: Conchoidal to uneven +diagnostic_features: "Strong trichroism (green/yellow/red-brown) — primary diagnostic; clearly visible in dichroscope; biaxial negative; SG 3.27-3.45; RI 1.661-1.683; cat's-eye variety from Sri Lanka and Tanzania" +pleochroism: Strong trichroism +pleochroism_strength: strong +pleochroism_color1: Green +pleochroism_color2: Yellow +pleochroism_notes: Third direction red-brown; Sri Lanka material may show green/colourless/yellow-brown trichroism +colors: +- Green +- Yellowish-green +- Brown +- Rarely colourless +treatments: +- None known in trade +localities: +- Sri Lanka (primary; alluvial gravels, Elahera, Ratnapura) +- Madagascar (gem-quality transparent green) +- Tanzania (gem material; cat's-eye variety) +- Myanmar (Burma; minor) +- Greenland (type locality; large crystals mostly opaque; named for geological explorer Kornerup) +inclusions: +- Cat's-eye material: dense parallel hollow tubes or fibrous inclusions +- Liquid inclusions; growth planes +- Occasional mineral inclusions +notes: > + Mg-Al-Fe boroaluminosilicate; orthorhombic mmm; complex formula with IMA species kornerupine + (<=0.5 B per formula unit) and prismatine (>0.5 B; separate IMA species since 1997). + Optical constants and cat's-eye kornerupine from Sri Lanka confirmed by Zwaan 1996, + Gems & Gemology 32(4):262-269 (DOI 10.5741/gems.32.4.262) [VERIFIED]. + Elahera gem field confirmed by Gunawardene & Rupasinghe 1986 (DOI 10.5741/gems.22.2.80) + [VERIFIED]. Gem localities by Shigley et al. 2000 (DOI 10.5741/gems.36.4.292) [VERIFIED]. + Strong trichroism (green/yellow/red-brown) is the primary field diagnostic; + "immediately recognisable under the dichroscope." Colour cause: Fe2+ (green); Cr3+ in + intensely green stones. Cat's-eye variety: fibrous hollow tubes parallel to c-axis. +expressions: +- slug: default + name: Kornerupine + cdl: | + #! Species: Kornerupine + #! System: Orthorhombic (mmm) + #! Habit: Elongated prismatic with strong trichroism + orthorhombic[mmm]:{110}@1.0 + {010}@0.6 + {001}@0.4 + is_primary: true + form_description: > + Orthorhombic Mg-Al boroaluminosilicate; elongated prismatic habit. Strong trichroism + (green/yellow/red-brown) visible in dichroscope is the primary diagnostic. Sri Lanka and + Madagascar are the main gem sources. Biaxial negative. + forms: + - prism + - pinacoid +- slug: cats-eye + name: Cat's-Eye Kornerupine + cdl: | + #! Species: Cat's-Eye Kornerupine + #! System: Orthorhombic (mmm) + #! Habit: Fibrous inclusions parallel to c-axis produce chatoyancy + orthorhombic[mmm]:{110}@1.0 + {001}@0.5[inclusion:fibrous_tubes] + is_primary: false + form_description: Chatoyant variety; fine fibrous hollow tube inclusions parallel to c-axis. + forms: + - prism diff --git a/data/source/minerals/maw-sit-sit.yaml b/data/source/minerals/maw-sit-sit.yaml new file mode 100644 index 0000000..389e709 --- /dev/null +++ b/data/source/minerals/maw-sit-sit.yaml @@ -0,0 +1,57 @@ +id: maw-sit-sit +name: Maw-Sit-Sit +crystal_system: monoclinic +point_group: 2/m +chemistry: Multi-mineral rock aggregate; dominant phases kosmochlor (NaCrSi2O6) + jadeite (NaAlSi2O6) + albite (NaAlSi3O8) + chromite (FeCr2O4) +mineral_group: Jade group (multi-mineral pyroxene rock) +category: Ornamental rocks +origin: natural +hardness: 6-7 +sg: 3.00-3.40 +ri: 1.52-1.68 +birefringence: null +optical_character: AGG +lustre: Waxy to vitreous +cleavage: None (polycrystalline aggregate) +fracture: Splintery to uneven +diagnostic_features: "Vivid emerald-green matrix with black to dark green spots or streaks (chromite inclusions); Chelsea filter strongly red (Cr3+); RI aggregate reading typically 1.52-1.68 (varies by phase); SG 3.00-3.40 (heavier than jadeite 3.34 average due to chromite); Myanmar (Kachin State) as only commercial source" +pleochroism: None (aggregate) +colors: +- Vivid emerald-green to bright green (kosmochlor/jadeite matrix; Cr3+ chromophore) +- With black to dark green spots and veins (chromite + kosmochlor-rich zones) +treatments: +- Generally not treated; waxing occasionally for surface stabilisation +localities: +- Myanmar (Kachin State, Tawmaw area; only commercial source) +inclusions: +- Chromite crystals (diagnostic black to dark green spots) +- Albite-rich feldspar patches +- Kosmochlor-jadeite intergrowths +notes: > + Multi-mineral decorative rock; NOT a single IMA mineral species. Dominant mineralogy: + kosmochlor (NaCrSi2O6, a chromium pyroxene, monoclinic 2/m) + jadeite (NaAlSi2O6, + monoclinic 2/m) + albite + chromite. Crystal system assigned as monoclinic (dominant + pyroxene phase). First described by Gübelin 1965, Journal of Gemmology + (DOI 10.15506/jog.1965.9.10.329) [VERIFIED]. Mineralogical composition confirmed by + Harlow et al. 2000 (DOI 10.15506/jog.2000.27.2.87) [VERIFIED] and Ou Yang et al. 2025 + (DOI 10.3390/cryst15110983) [VERIFIED]. + CAUTION: This is a polycrystalline multi-mineral rock aggregate — RI, SG, and hardness + are composite values depending on the mix of phases. The Chelsea filter red reaction is + from Cr3+ in kosmochlor. Often confused with jadeite but the chromite spots and higher Cr + content distinguish it. Not a standard jade variety. +expressions: +- slug: default + name: Maw-Sit-Sit + cdl: | + #! Species: Maw-Sit-Sit (kosmochlor-jadeite rock) + #! System: Monoclinic (2/m; dominant pyroxene phase proxy) + #! Habit: Massive aggregate; vivid green with black chromite inclusions + monoclinic[2/m]:{110}@1.0 + {010}@0.5[inclusion:chromite] + is_primary: true + form_description: > + Polycrystalline multi-mineral rock (kosmochlor + jadeite + albite + chromite) from Kachin State, + Myanmar. Vivid emerald-green matrix with black to dark green chromite spots. CDL represents the + dominant monoclinic pyroxene (kosmochlor/jadeite) phase as proxy for the aggregate. Not an IMA + mineral species; included as gem material per FGA/Diploma curriculum coverage. + forms: + - massive diff --git a/data/source/minerals/maxixe-beryl.yaml b/data/source/minerals/maxixe-beryl.yaml new file mode 100644 index 0000000..38582aa --- /dev/null +++ b/data/source/minerals/maxixe-beryl.yaml @@ -0,0 +1,65 @@ +id: maxixe-beryl +name: Maxixe-type Beryl +crystal_system: hexagonal +point_group: 6/mmm +chemistry: Be3Al2Si6O18 +mineral_group: Beryl group +category: Cyclosilicates +origin: natural +hardness: 7.5-8 +sg: 2.68-2.76 +ri: 1.563-1.578 +birefringence: 0.005-0.008 +optical_character: Uniaxial - +dispersion: 0.014 +lustre: Vitreous +cleavage: Imperfect basal +fracture: Conchoidal +diagnostic_features: "Deep navy to inky blue much more saturated than aquamarine; strong dichroism deep blue/colourless (stronger than aquamarine blue-green/colourless); CRITICAL: colour FADES on prolonged light exposure (sunlight/UV) — aquamarine does NOT fade; absorption spectrum differs from aquamarine (CO3-related bands ~575, 610, 650-700 nm vs Fe2+ in aquamarine)" +pleochroism: Strong dichroism +pleochroism_strength: strong +pleochroism_color1: Deep blue (ordinary ray) +pleochroism_color2: Colourless to pale blue (extraordinary ray) +colors: +- Deep navy to inky blue (much more saturated than aquamarine) +treatments: +- The colour itself IS a treatment in commercially sold Maxixe-type (artificial irradiation of colourless or pale beryl) +- DISCLOSURE OBLIGATION: must be disclosed as irradiated colour that fades; failure is a trade ethics violation +localities: +- Brazil (Maxixe mine, Minas Gerais; type locality for naturally irradiated blue beryl; mostly exhausted) +- Russia (Ural; possible occurrence per Andersson 2011) +- Any beryl from any locality can produce Maxixe-type colour by artificial irradiation treatment +inclusions: +- Natural Maxixe beryl: natural fluid inclusions typical of Brazilian beryl +- Irradiated Maxixe-type: inclusions of the host beryl +notes: > + Irradiation-induced deep blue colour variety of beryl (Be3Al2Si6O18). Chemistry per + VERIFIED.md conflict resolution F-01: correct cyclosilicate formula Be3Al2Si6O18 + (NOT Be3Al2(SiO3)6). Colour centre: CO3^2- or NO3^- ions in beryl channels are + irradiated to create the colour centre. NOT caused by Fe2+ (as in aquamarine). + Confirmed by Adamo, Pavese et al. 2008, Gems & Gemology 44(3):214-226 + (DOI 10.5741/gems.44.3.214) [VERIFIED via live API]: primary modern reference + differentiating Maxixe-type from aquamarine and synthetic blue beryl. Also Andersson 2011, + Journal of Gemmology 32(5):145 (DOI 10.15506/jog.2011.32.5.145) [VERIFIED]. + Colour centre mechanism: Fritsch & Rossman 1988 (DOI 10.5741/gems.24.1.3) [VERIFIED]. + CRITICAL TRADE ISSUE: Maxixe-type colour FADES upon prolonged light exposure (UV/sunlight). + Aquamarine does NOT fade. This is the single most critical trade distinction. + UV lamp test (24-48 hours): Maxixe-type shows noticeable fading; aquamarine unchanged. + Disclosure as irradiated fading colour is mandatory. Store in dark; warn customer. +expressions: +- slug: default + name: Maxixe-type Beryl (Irradiated Blue) + cdl: | + #! Species: Maxixe-type Beryl (Be3Al2Si6O18; irradiated colour variety) + #! System: Hexagonal (6/mmm) + #! Habit: Prismatic hexagonal; deep navy-blue irradiation colour centre + hexagonal[6/mmm]:{10-10}@1.0 + {0001}@0.6 + is_primary: true + form_description: > + Deep navy-blue variety of beryl; colour from irradiation-induced CO3/NO3 colour centre. + Identical crystal habit to aquamarine/goshenite (hexagonal prismatic). Strong dichroism + (deep blue / colourless). Colour fades in light — critical disclosure obligation. + Maxixe mine, Minas Gerais, Brazil is the type natural locality. + forms: + - prism + - pinacoid diff --git a/data/source/minerals/moldavite.yaml b/data/source/minerals/moldavite.yaml new file mode 100644 index 0000000..8fe6c57 --- /dev/null +++ b/data/source/minerals/moldavite.yaml @@ -0,0 +1,62 @@ +id: moldavite +name: Moldavite +crystal_system: amorphous +point_group: none +chemistry: SiO2-rich glass (>70 wt% SiO2) + Al2O3, MgO, FeO, CaO, K2O, Na2O (natural impact glass; composition variable) +mineral_group: Tektites (impactites) +category: Mineraloids +origin: natural +hardness: 5-5.5 +sg: 2.32-2.38 +ri: 1.480-1.510 +birefringence: null +optical_character: Isotropic +dispersion: null +lustre: Vitreous to greasy +cleavage: None +fracture: Conchoidal +diagnostic_features: "Characteristic wrinkled/pitted/sculptured surface (aerodynamic ablation during atmospheric flight after Ries impact); schlieren (flow banding) under magnification; elongated gas bubbles; SG 2.32-2.38 (lower than obsidian 2.40-2.55); RI 1.480-1.510; bottle-green colour from Fe2+" +pleochroism: None +colors: +- Bottle green to olive green (Fe2+ in glass) +- Brownish-green +- Rarely pale green +treatments: +- Minimal (cleaning and polishing) +- Fakes: manufactured green glass and pressed pieces from chips — distinguished by sculptured surface (natural) vs uniform surface (fake) +localities: +- Czech Republic (south and west Bohemia, southern Moravia; primary strewn field) +- Germany (Ries crater area, Bavaria; Nördlingen Ries bolide impact ~14.7 Ma) +- Poland (rare re-deposited specimens) +inclusions: +- Lechatelierite (pure silica glass schlieren and tubes; diagnostic of high-temperature fusion) +- Gas bubbles (round to elongated) +- Occasional relict mineral grains (zircon, chromite) from target rocks +notes: > + Natural tektite (impactite glass); NOT an IMA mineral species (tektites are not crystalline + minerals per IMA definition). Formed by Nördlingen Ries bolide impact, southeastern Germany, + ~14.7 Ma; strewn field in Bohemia and Moravia, Czech Republic. + Included in mineral-DB as gem material per FGA Foundation/Diploma curriculum coverage. + Per VERIFIED.md decision: ship as amorphous entry with clear notes that it is a non-IMA + species (same convention as opal which is also amorphous). IMA-approved: No. + Tektite strewn-field research: (DOI 10.3190/jgeosci.214) [PARTIALLY_SUPPORTED]. + Gem localities context: Shigley et al. 2000 (DOI 10.5741/gems.36.4.292) [VERIFIED]. + SG 2.32-2.38 lower than obsidian (2.40-2.55); RI 1.480-1.510 from Read 7th ed. + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. +expressions: +- slug: natural + name: Moldavite (Natural Tektite) + cdl: | + #! Species: Moldavite (tektite glass; non-IMA) + #! System: Amorphous (impactite glass) + #! Habit: Irregular sculptured masses from aerodynamic ablation + amorphous[glassy]:{massive} + is_primary: true + form_description: > + Natural tektite glass from the Nördlingen Ries impact event (~14.7 Ma). Amorphous; isotropic. + Characteristic sculptured/pitted surface from aerodynamic ablation. Bottle-green colour from + Fe2+. NOT an IMA mineral species — included as gem material per FGA curriculum coverage. + Lechatelierite schlieren and gas bubbles are diagnostic internal features. + forms: + - massive + - irregular diff --git a/data/source/minerals/musgravite.yaml b/data/source/minerals/musgravite.yaml new file mode 100644 index 0000000..6d4e081 --- /dev/null +++ b/data/source/minerals/musgravite.yaml @@ -0,0 +1,65 @@ +id: musgravite +name: Musgravite +crystal_system: hexagonal +point_group: "-3m" +chemistry: BeMg2Al6O12 +mineral_group: Taaffeite group (spinel supergroup) +category: Oxides +origin: natural +hardness: 8-8.5 +sg: 3.61-3.68 +ri: 1.719-1.736 +birefringence: 0.004-0.012 +optical_character: Uniaxial - +dispersion: null +lustre: Vitreous +cleavage: None +fracture: Conchoidal +diagnostic_features: "Doubly refractive (uniaxial negative) — separates from spinel (isotropic); slightly higher RI and SG than taaffeite (SG overlap exists); ATR-FTIR and Raman spectroscopy give definitive separation from taaffeite by vibrational band positions. One of the rarest gem minerals." +pleochroism: Weak +pleochroism_strength: weak +pleochroism_color1: Grey-green +pleochroism_color2: Colourless to pale olive +colors: +- Grey-green +- Olive green +- Violet +- Colourless (extremely rare) +treatments: +- None known +localities: +- Australia (Musgrave Ranges, South Australia; type locality; 1967 discovery) +- Sri Lanka (several reported stones) +- Madagascar +- Tanzania +- Greenland (minor) +inclusions: +- Generally very clean +notes: > + BeMg2Al6O12; hexagonal, rhombohedral, point group -3m. IMA revised name: + magnesiotaaffeite-6N'3S per Armbruster 2002 (DOI 10.1127/0935-1221/2002/0014-0389) + [VERIFIED via live API]. ATR-FTIR and Raman distinction from taaffeite confirmed by + Thongnopkun 2024 (DOI 10.1016/j.vibspec.2024.103733) [VERIFIED via live API]: + "ATR-FTIR and Raman spectroscopy efficiently distinguish musgravite from taaffeite + using diagnostic vibrational band positions." Higher RI (1.719-1.736) and SG (3.61-3.68) + than taaffeite (RI 1.717-1.730, SG 3.60-3.62) but ranges overlap; FTIR/Raman is + definitive. Colour cause: Cr, Fe or V substitution (not firmly established for all colours; + per VERIFIED.md REJ-07, do not present as confirmed fact). Type locality: Musgrave Ranges, + South Australia; fewer than 10 faceted stones known before 2000. + Note: musgravite is a separate IMA species from taaffeite, not merely a variety. +expressions: +- slug: default + name: Musgravite + cdl: | + #! Species: Musgravite (magnesiotaaffeite-6N'3S) + #! System: Hexagonal (-3m; rhombohedral) + #! Habit: Alluvial rounded to subhedral grains + trigonal[-3m]:{10-10}@1.0 + {0001}@0.5 + {10-11}@0.7 + is_primary: true + form_description: > + BeMg2Al6O12; hexagonal (trigonal rhombohedral). One of the rarest faceted gem minerals. + Birefringent (uniaxial negative); distinguishes from spinel (isotropic) on polariscope. + Separated from taaffeite by FTIR/Raman; slightly higher RI and SG but ranges overlap. + Type locality: Musgrave Ranges, South Australia (1967). + forms: + - rhombohedron diff --git a/data/source/minerals/obsidian.yaml b/data/source/minerals/obsidian.yaml new file mode 100644 index 0000000..2e593f7 --- /dev/null +++ b/data/source/minerals/obsidian.yaml @@ -0,0 +1,73 @@ +id: obsidian +name: Obsidian +crystal_system: amorphous +point_group: none +chemistry: SiO2 (55-75 wt%) + Al2O3, FeO, MgO, CaO, Na2O, K2O (rhyolitic volcanic glass; variable) +mineral_group: Mineraloid / Natural glass +category: Mineraloids +origin: natural +hardness: 5-5.5 +sg: 2.33-2.50 +ri: 1.48-1.51 +birefringence: null +optical_character: Isotropic (ADR in stressed varieties) +lustre: Vitreous to sub-vitreous +cleavage: None +fracture: Conchoidal (sharp edges; most diagnostic macroscopic feature) +diagnostic_features: "Conchoidal fracture (primary); flow banding under magnification; RI 1.48-1.51; SG 2.33-2.50 (lower than most gem minerals); isotropic under polariscope" +pleochroism: None +colors: +- Black (magnetite crystallites) +- Mahogany (red-brown hematite patches in black matrix) +- Snowflake (cristobalite spherulites in black matrix) +- Golden or silver sheen (oriented gas bubble layers) +- Rainbow/fire (thin-film interference in layered glass) +treatments: +- Surface coatings (occasional; detected by acetone test) +localities: +- Mexico (Hidalgo, Jalisco, Michoacan; rainbow and snowflake varieties) +- USA (Glass Buttes Oregon; Obsidian Cliff Wyoming) +- Armenia (Satanakar, Geghasar; major prehistoric trade source) +- Iceland (Hekla volcano) +- Italy (Lipari, Sardinia) +- Ethiopia (Hareri region; East African Rift) +- New Zealand (Mayor Island) +inclusions: +- Sub-microscopic magnetite/hematite crystallites +- Cristobalite spherulites (snowflake obsidian) +- Oriented gas bubble layers (sheen varieties) +- Flow banding +- Phenocryst fragments (sanidine, plagioclase, pyroxene) +notes: > + Not an IMA mineral species; natural volcanic glass (mineraloid) formed by rapid solidification + of rhyolitic to rhyodacitic lava. IMA-approved: N/A. Flow banding and conchoidal fracture + confirmed by Zook (1973) Journal of Gemmology (DOI 10.15506/jog.1973.13.6.220) [VERIFIED]. + Van Nostrand's Scientific Encyclopedia chapter (DOI 10.1002/0471743984.vse5189) [VERIFIED]. + RI and SG from Read 7th ed. (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. + Snowflake obsidian: cristobalite variety. Sheen: oriented gas bubble interference. +expressions: +- slug: default + name: Obsidian + cdl: | + #! Species: Obsidian (volcanic glass) + #! System: Amorphous (mineraloid) + #! Habit: Massive with conchoidal fracture; flow structures + amorphous[glassy]:{massive} + is_primary: true + form_description: > + Natural volcanic glass; amorphous silicic mineraloid. Massive habit with diagnostic conchoidal + fracture and flow banding. Varieties include snowflake (cristobalite spherulites), + mahogany (hematite), sheen (gas bubbles), and rainbow (thin-film layering). + forms: + - massive +- slug: snowflake + name: Snowflake Obsidian + cdl: | + #! Species: Snowflake Obsidian + #! System: Amorphous + #! Habit: Black glass matrix with white cristobalite spherulites + amorphous[glassy]:{massive}[inclusion:spherulitic] + is_primary: false + form_description: Black obsidian with white to grey cristobalite spherulite inclusions forming snowflake pattern. + forms: + - massive diff --git a/data/source/minerals/scapolite.yaml b/data/source/minerals/scapolite.yaml new file mode 100644 index 0000000..5baef94 --- /dev/null +++ b/data/source/minerals/scapolite.yaml @@ -0,0 +1,79 @@ +id: scapolite +name: Scapolite +crystal_system: tetragonal +point_group: 4/m +chemistry: (Na,Ca)4Al3(Al,Si)3Si6O24(Cl,CO3,SO4) +mineral_group: Scapolite group (tectosilicates / feldspathoid-related) +category: Tectosilicates +origin: natural +hardness: 5.5-6 +sg: 2.50-2.78 +ri: 1.536-1.600 +birefringence: 0.004-0.037 +optical_character: Uniaxial - +dispersion: null +lustre: Vitreous +cleavage: Distinct prismatic in two directions {100} and {110} +fracture: Conchoidal to uneven +diagnostic_features: "Uniaxial negative; strong LWUV fluorescence (yellow to orange in yellow stones; diagnostic — chrysoberyl cat's-eye does not fluoresce strongly); moderate birefringence; cat's-eye variety from Myanmar is celebrated; SG 2.50-2.78" +pleochroism: Weak to moderate (uniaxial; dichroic; colourless/yellow in yellow stones; stronger in violet) +pleochroism_strength: weak +pleochroism_color1: Yellow to orange +pleochroism_color2: Colourless to pale yellow +colors: +- Yellow (most common gem colour; colour centres) +- Pink/lilac/violet (Tanzania) +- Colourless (marialite-rich) +- Cat's-eye (chatoyant; parallel hollow tubes) +treatments: +- Not routinely treated; some material reportedly irradiated to enhance colour +localities: +- Myanmar (Burma; fine cat's-eye scapolite) +- Madagascar (Ihosy; yellow transparent) +- Tanzania (pink and violet) +- Sri Lanka (various including cat's-eye) +- Brazil (colourless to yellow) +- Kenya +inclusions: +- Cat's-eye: dense parallel hollow tubes/fibrous inclusions +- Two-phase fluid inclusions; growth planes +- Myanmar material: parallel needle inclusions +notes: > + Na-Ca aluminosilicate solid solution series (marialite to meionite); tetragonal 4/m. + Yellow scapolite from Madagascar confirmed by Superchi et al. 2010, Gems & Gemology + 46(4):274-279 (DOI 10.5741/gems.46.4.274) [VERIFIED]. Cat's-eye and unusual properties + from Sri Lanka confirmed by Zwaan 1996, Gems & Gemology 32(4):262-269 + (DOI 10.5741/gems.32.4.262) [VERIFIED]. Colour cause in yellow stones: colour centres + (F-centres; not transition metal ions) — Fritsch & Rossman 1988 + (DOI 10.5741/gems.24.1.3) [VERIFIED]. Strong LWUV fluorescence (yellow-orange) is a + key diagnostic. Two prismatic cleavage directions complicate faceting. +expressions: +- slug: prismatic + name: Scapolite (Prismatic) + cdl: | + #! Species: Scapolite (Marialite-Meionite series) + #! System: Tetragonal (4/m) + #! Habit: Prismatic tetragonal crystals + tetragonal[4/m]:{110}@1.0 + {100}@0.6 + {001}@0.4 + is_primary: true + form_description: > + Tetragonal prismatic crystals; Na-Ca aluminosilicate solid-solution series (marialite–meionite). + Strong LWUV fluorescence in yellow material is diagnostic. Cat's-eye variety from Myanmar + (Burma) is most prized. Uniaxial negative optic character. + forms: + - prism + - dipyramid + - pinacoid +- slug: cats-eye + name: Cat's-Eye Scapolite + cdl: | + #! Species: Cat's-Eye Scapolite + #! System: Tetragonal (4/m) + #! Habit: Prismatic; fibrous inclusions produce chatoyancy in cabochon + tetragonal[4/m]:{110}@1.0 + {100}@0.6[inclusion:fibrous_tubes] + is_primary: false + form_description: > + Chatoyant variety; dense parallel hollow tubes and/or fibrous inclusions produce a sharp + cat's-eye in cabochon cut. Burma (Myanmar) is the reference locality for gem-quality cat's-eye. + forms: + - prism diff --git a/data/source/minerals/serpentine.yaml b/data/source/minerals/serpentine.yaml new file mode 100644 index 0000000..f3e7247 --- /dev/null +++ b/data/source/minerals/serpentine.yaml @@ -0,0 +1,80 @@ +id: serpentine +name: Serpentine +crystal_system: monoclinic +point_group: 2/m +chemistry: Mg3Si2O5(OH)4 +mineral_group: Serpentine group (phyllosilicates) +category: Phyllosilicates +origin: natural +hardness: 2.5-5 +sg: 2.44-2.62 +ri: 1.55-1.57 +birefringence: null +optical_character: AGG +dispersion: null +lustre: Waxy to greasy +cleavage: Perfect (single plane in antigorite); fracture conchoidal to uneven in massive material +fracture: Conchoidal to uneven +diagnostic_features: "Waxy lustre (most distinctive visual feature); low hardness H 2.5-5 (scratched by knife — critical separator from true jade); RI 1.55-1.57 (much lower than jadeite 1.66 or nephrite 1.62); low SG 2.44-2.62 (lighter than jadeite 3.34 or nephrite 2.90-3.10); chromite inclusions in williamsite" +pleochroism: None +colors: +- Apple green to yellow-green (bowenite; Fe2+/Fe3+ chromophore) +- Oil-green to chrome-green (williamsite; Cr3+ substituting Mg) +- Grey-green to mottled green, white, pale bluish-green (various antigorite) +- Veined/patterned (serpentinite rock with magnetite or chromite veining) +treatments: +- Wax/oil impregnation (common) +- Dyeing (green colour enhancement) +- Polymer stabilisation +localities: +- Rhode Island, USA (Smithfield; type locality for bowenite; named after George T. Bowen) +- New Zealand (Maori pounamu; bowenite alongside nephrite) +- Afghanistan (Kandahar; translucent apple-green bowenite) +- Pennsylvania and Maryland, USA (williamsite; Chrome, Chester County) +- Cornwall, England +- Connemara, Ireland (Connemara marble; green serpentine marble) +- Pakistan, India, China, Korea, South Africa +inclusions: +- Chromite grains (black to brown; diagnostic in bowenite/williamsite) +- Magnetite granules +- Antigorite plate-like crystal bundles +- Talc patches +- Chrysotile veinlets +notes: > + Principal IMA-approved gem species is antigorite (monoclinic 2/m); lizardite is trigonal + (-3m) — both formula Mg3Si2O5(OH)4 with Mg:Fe and Cr substitution. Gem material is invariably + polycrystalline massive aggregate; crystal system given for the dominant antigorite (bowenite) + phase. Chrysotile (fibrous asbestiform variety) is NOT used as gem material. + Chemical formula and mineral group confirmed by Ross & Shannon 1962, USGS Professional Paper + 384-A (DOI 10.3133/pp384a) [VERIFIED]. RI and SG from Read 7th ed. (DOI 10.4324/9780080507224) + [PARTIALLY_SUPPORTED]. Serpentine as jade simulant ("New jade" trade name) documented by + Hobbs 1982, Gems & Gemology (DOI 10.5741/gems.18.1.3) [VERIFIED]. + Trade name "New jade" is misleading; material is not jadeite or nephrite. +expressions: +- slug: bowenite + name: Bowenite (Gem Serpentine) + cdl: | + #! Species: Serpentine (Antigorite/Bowenite variety) + #! System: Monoclinic (2/m) + #! Habit: Massive aggregate; waxy green + monoclinic[2/m]:{001}@1.0 + {100}@0.7 + is_primary: true + form_description: > + Bowenite variety of antigorite; translucent apple-green massive aggregate with waxy lustre. + Polycrystalline — CDL represents the dominant antigorite phase. Used as jade simulant but + easily distinguished by low RI, SG, and hardness. + forms: + - massive +- slug: williamsite + name: Williamsite (Chromian Serpentine) + cdl: | + #! Species: Williamsite (Cr-bearing serpentine) + #! System: Monoclinic (2/m) + #! Habit: Massive aggregate; oil-green with chromite inclusions + monoclinic[2/m]:{001}@1.0 + {100}@0.5[inclusion:chromite] + is_primary: false + form_description: > + Chromian variety of antigorite (williamsite); oil-green colour from Cr3+ substitution; + black chromite grain inclusions diagnostic. Pennsylvania, USA type locality. + forms: + - massive diff --git a/data/source/minerals/sinhalite.yaml b/data/source/minerals/sinhalite.yaml new file mode 100644 index 0000000..15e5c06 --- /dev/null +++ b/data/source/minerals/sinhalite.yaml @@ -0,0 +1,59 @@ +id: sinhalite +name: Sinhalite +crystal_system: orthorhombic +point_group: mmm +chemistry: MgAlBO4 +mineral_group: Borates (olivine-structure type) +category: Borates +origin: natural +hardness: 6.5 +sg: 3.46-3.50 +ri: 1.668-1.707 +birefringence: 0.038 +optical_character: Biaxial - +dispersion: null +lustre: Vitreous +cleavage: Imperfect +fracture: Conchoidal +diagnostic_features: "Biaxial negative (peridot is biaxial positive — the key optic-sign diagnostic); higher SG 3.46-3.50 vs peridot 3.27-3.37; high birefringence 0.038; differentiated from peridot by optic sign, SG, and absorption spectrum differences (Fe2+ band profile differs)" +pleochroism: Moderate +pleochroism_strength: moderate +pleochroism_color1: Brownish-green +pleochroism_color2: Pale green to yellowish +colors: +- Pale yellow-brown +- Brownish-green +- Greenish-brown +- Rarely yellowish +treatments: +- None known +localities: +- Sri Lanka (primary; alluvial gem gravels, Ratnapura district) +- Myanmar (Burma; minor) +- Tanzania (trace occurrences) +inclusions: +- Generally clean; fluid inclusions possible +notes: > + MgAlBO4; orthorhombic mmm; olivine-structure type borate. Named from Sinhala (= Sri Lanka). + Formally described as a distinct mineral species in 1952; previously confused with brown peridot. + Key distinction from peridot: biaxial negative optic sign (peridot is biaxial positive); higher + SG 3.46-3.50 (peridot 3.27-3.37). Sri Lanka alluvial occurrence confirmed by Zwaan 1982, + Gems & Gemology 18(2):62-71 (DOI 10.5741/gems.18.2.62) [VERIFIED] and Shigley et al. 2000 + (DOI 10.5741/gems.36.4.292) [VERIFIED]. Constants from Read 7th ed. + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. +expressions: +- slug: default + name: Sinhalite + cdl: | + #! Species: Sinhalite (MgAlBO4) + #! System: Orthorhombic (mmm) + #! Habit: Prismatic; olivine-structure type + orthorhombic[mmm]:{110}@1.0 + {010}@0.7 + {021}@0.5 + is_primary: true + form_description: > + Orthorhombic borate with olivine-type structure. Pale yellow-brown to brownish-green gem. + Biaxial negative (key distinction from biaxial positive peridot). Sri Lanka alluvials are the + primary source. High birefringence (0.038) produces visible doubling in deeper stones. + forms: + - prism + - pinacoid diff --git a/data/source/minerals/star-diopside.yaml b/data/source/minerals/star-diopside.yaml new file mode 100644 index 0000000..7f09a63 --- /dev/null +++ b/data/source/minerals/star-diopside.yaml @@ -0,0 +1,57 @@ +id: star-diopside +name: Star Diopside +crystal_system: monoclinic +point_group: 2/m +chemistry: CaMgSi2O6 +mineral_group: Pyroxene group +category: Inosilicates +origin: natural +hardness: 5.5-6 +sg: 3.27-3.38 +ri: 1.664-1.701 +birefringence: 0.024-0.031 +optical_character: Biaxial + +dispersion: null +lustre: Sub-vitreous +cleavage: Two perfect {110} pyroxene cleavages at ~90° +fracture: Uneven +diagnostic_features: "Four-rayed star (NOT six-rayed as in corundum) in reflected light; very dark to black body colour from dense magnetite needles; strongly magnetic (attracted to neodymium magnet — from magnetite inclusions; highly diagnostic); biaxial positive (unlike star garnet which is isotropic)" +pleochroism: None (opaque to near-opaque) +colors: +- Black to very dark green body colour (dense magnetite needle inclusions) +- White to grey four-rayed star in reflected light +treatments: +- None (natural star) +localities: +- India (primary and essentially exclusive commercial source; Tamil Nadu, Madhya Pradesh, Mysore/Karnataka area) +inclusions: +- Dense magnetite (Fe3O4) needle inclusions in two crystallographic directions perpendicular to c-axis and in the (100) plane +- The two-direction magnetite arrangement (not three as in corundum) produces the four-rayed (not six-rayed) star +notes: > + Black star diopside; variety of diopside (CaMgSi2O6) with dense magnetite (Fe3O4) needle + inclusions producing a four-rayed asterism in cabochon cut. Monoclinic 2/m (same crystal + system as chrome-diopside.yaml and main diopside.yaml entry). Note: this file is the star + variety; diopside.yaml is the general species entry. Use id: star-diopside to avoid collision. + Four-rayed star (not six-rayed) because monoclinic symmetry gives two sets of magnetite needle + orientations rather than three (as in hexagonal corundum). Strongly magnetic due to magnetite + inclusions — use neodymium magnet for rapid identification. India as primary source confirmed + by Shigley et al. 2000 (DOI 10.5741/gems.36.4.292) [VERIFIED]. Unusual properties of + diopside/enstatite from Sri Lanka confirmed by Zwaan 1996 + (DOI 10.5741/gems.32.4.262) [VERIFIED]. Constants from Read 7th ed. + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. +expressions: +- slug: star-cabochon + name: Star Diopside (Cabochon) + cdl: | + #! Species: Star Diopside (CaMgSi2O6) + #! System: Monoclinic (2/m) + #! Habit: Massive; magnetite needles in two directions produce four-rayed star + monoclinic[2/m]:{110}@1.0 + {010}@0.5[inclusion:magnetite_needles] + is_primary: true + form_description: > + Black star diopside; monoclinic 2/m pyroxene. Asterism from magnetite needle inclusions in two + crystallographic directions — produces four-rayed star (not six-rayed as in corundum). + Very dark to black body colour. Strongly magnetic (neodymium magnet test is rapid diagnostic). + Almost exclusively from India (Tamil Nadu/Madhya Pradesh). + forms: + - massive diff --git a/data/source/minerals/taaffeite.yaml b/data/source/minerals/taaffeite.yaml new file mode 100644 index 0000000..de61457 --- /dev/null +++ b/data/source/minerals/taaffeite.yaml @@ -0,0 +1,69 @@ +id: taaffeite +name: Taaffeite +crystal_system: hexagonal +point_group: "-3m" +chemistry: BeMgAl4O8 +mineral_group: Taaffeite group (spinel supergroup) +category: Oxides +origin: natural +hardness: 8-8.5 +sg: 3.60-3.62 +ri: 1.717-1.730 +birefringence: 0.004-0.009 +optical_character: Uniaxial - +dispersion: null +lustre: Vitreous +cleavage: None +fracture: Conchoidal +diagnostic_features: "Doubly refractive (uniaxial negative) — primary diagnostic; immediately separates from spinel (singly refractive, isotropic on polariscope). SG 3.60-3.62 overlaps spinel (3.58-3.65) making SG alone insufficient for separation. FTIR and Raman spectroscopy are the modern definitive identification tools (distinguish from musgravite)." +pleochroism: Weak (violet specimens may show slight dichroism colourless/pale violet) +pleochroism_strength: weak +pleochroism_color1: Pale violet +pleochroism_color2: Colourless +colors: +- Mauve to pale violet (most common gem colour) +- Pink +- Red +- Blue-green (rare) +- Colourless (rare) +treatments: +- None known +localities: +- Sri Lanka (historic and primary; alluvial gem gravels, Ratnapura) +- Myanmar (Burma/Mogok; small amounts) +- Tanzania +- China (very minor) +inclusions: +- Generally very clean; FTIR and Raman are the most reliable modern ID tools +notes: > + BeMgAl4O8; hexagonal, rhombohedral subgroup, point group -3m. IMA revised name: + magnesiotaaffeite-2N'2S per Armbruster 2002 (DOI 10.1127/0935-1221/2002/0014-0389) + [VERIFIED via live API]. Gemmological constants and analytical identification confirmed by + Thongnopkun 2024 (DOI 10.1016/j.vibspec.2024.103733) [VERIFIED via live API]. + CRITICAL DIAGNOSTIC NOTE (per VERIFIED.md Conflict 7 + flag F-05): Doubly refractive + (uniaxial negative) — this is the primary and immediate separation from spinel (isotropic). + SG 3.60-3.62 overlaps spinel (3.58-3.65); SG alone is NOT sufficient for separation. + RI 1.717-1.730 also overlaps with some spinel specimens. The polariscope (DR test) is the + definitive field separation. ATR-FTIR and Raman distinguish taaffeite from musgravite + (magnesiotaaffeite-6N'3S) by vibrational band positions. Musgravite: higher SG ~3.61-3.68, + higher RI ~1.723-1.736; see separate musgravite.yaml entry. Historical note: Edward Taaffe + purchased the original stone in a Dublin gem dealer's parcel in 1945, believing it spinel; + the double refraction was noticed and confirmed as a new species in 1951. + Gem localities confirmed by Shigley et al. 2000 (DOI 10.5741/gems.36.4.292) [VERIFIED]. +expressions: +- slug: default + name: Taaffeite + cdl: | + #! Species: Taaffeite (magnesiotaaffeite-2N'2S) + #! System: Hexagonal (-3m; rhombohedral) + #! Habit: Rounded to subhedral from alluvial reworking + trigonal[-3m]:{10-10}@1.0 + {0001}@0.5 + {10-11}@0.7 + is_primary: true + form_description: > + One of the rarest gem minerals; BeMgAl4O8; hexagonal (trigonal rhombohedral symmetry). + Birefringent (uniaxial negative) unlike isotropic spinel — polariscope DR test is the + primary separation. Most gem material is alluvially reworked (Sri Lanka, Myanmar). + FTIR/Raman required to distinguish from musgravite (magnesiotaaffeite-6N'3S). + forms: + - rhombohedron + - prism diff --git a/data/source/simulants/ambroid.yaml b/data/source/simulants/ambroid.yaml new file mode 100644 index 0000000..c21397a --- /dev/null +++ b/data/source/simulants/ambroid.yaml @@ -0,0 +1,51 @@ +id: ambroid +name: Ambroid (Pressed Amber) +crystal_system: amorphous +point_group: none +chemistry: Compressed and fused amber chips (same chemical composition as amber — fossil resin; succinite for Baltic amber) +category: amber simulant +origin: simulant +target_minerals_json: '["amber"]' +year_first_produced: "1880" +hardness: "2-2.5" +sg: "1.05-1.09" +ri: "1.530-1.545" +birefringence: 0 +optical_character: Isotropic +lustre: Resinous +cleavage: None +fracture: Conchoidal +colors: [Yellow, Orange-yellow, Orange; may show streaky swirling colour distribution from compression] +inclusions: [Elongated bubbles (from pressing process; diagnostic); streaky flow-lines; angular fragments of original amber chips visible under magnification at junction zones] +fluorescence: Blue-white (LWUV; similar to amber) +notes: > + Ambroid is a simulant produced by compressing/fusing small amber chips and fragments under + heat and pressure (autoclave compression); also called "reconstituted amber" or "pressed amber." + Same chemistry as amber; FTIR spectrum matches amber (Baltic succinite shoulder ~1150 cm-1 + present). Main diagnostic: elongated/flattened bubbles from pressing process (natural amber + has round spherical bubbles); streaky colour zones at chip boundaries visible under microscope; + angular junction planes between compressed fragments. Float test identical to amber (SG + 1.05-1.09). RI identical to amber (1.530-1.545). Acetone test: ambroid resists acetone + (like amber; fully polymerised) — distinguishes from copal. Gemmological knowledge from + Read 7th ed. (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. Introduced commercially + c.1880s when amber scrap from cutting was compressed to make larger pieces. + Note: ambroid is NOT an imitation of a different material — it IS amber (same composition) + but reconstituted; the "simulant" classification reflects its commercial deception as + "natural unmodified amber." Target: natural amber. +diagnostic_synthetic_features: > + Elongated flattened bubbles (vs spherical in natural amber — most diagnostic under microscope); + streaky colour zones at chip boundaries; angular junction planes between compressed fragments; + FTIR: same as amber (not distinguishable by FTIR alone); float/acetone tests same as amber +expressions: + - slug: default + name: Ambroid (Pressed Amber) + cdl: | + #! Species: Ambroid (reconstituted/pressed amber) + #! System: Amorphous (fossil resin) + #! Habit: Massive; streaky colour zones from compression + amorphous[resinous]:{massive} + is_primary: true + form_description: > + Compressed and fused amber chips; amorphous fossil resin. Same chemistry as amber; FTIR + cannot distinguish. Elongated flattened bubbles and angular chip-boundary zones visible + under magnification are diagnostic. Resists acetone (unlike copal). diff --git a/data/source/simulants/bone.yaml b/data/source/simulants/bone.yaml new file mode 100644 index 0000000..608f7ff --- /dev/null +++ b/data/source/simulants/bone.yaml @@ -0,0 +1,53 @@ +id: bone +name: Bone (Ivory Simulant) +crystal_system: amorphous +point_group: none +chemistry: Ca5(PO4)3(OH) (hydroxyapatite; same general composition as ivory dentine) in collagen matrix; technically microcrystalline hydroxyapatite but gemologically treated as amorphous/aggregate biomineral +category: ivory simulant +origin: simulant +target_minerals_json: '["ivory"]' +year_first_produced: "0" +hardness: "2-3" +sg: "1.70-2.00" +ri: "1.54-1.57" +birefringence: null +optical_character: AGG +lustre: Waxy to dull +cleavage: None +fracture: Conchoidal to splintery +colors: [White to cream-white; yellowing with age from collagen degradation; may be bleached] +inclusions: [Haversian canals (osteon structure; parallel pore-like dots in cross-section; diagnostic of bone; ABSENT in ivory); absent Schreger lines (ivory has them; bone does not)] +fluorescence: White-blue (LWUV; similar to ivory; not diagnostic for separation) +notes: > + Skeletal bone from domestic animals (cattle, pigs, horses); carved, bleached and polished + as ivory simulant. Crystal system set to amorphous (same convention as other organic/ + biomineral entries). Note: technically hydroxyapatite is hexagonal, but bone as a whole is + a composite biomineral (amorphous collagen + microcrystalline apatite) — gemologically + treated as amorphous aggregate. Primary separation from ivory confirmed by Jha et al. 2017, + Journal of Institute of Science and Technology 22(1):17745 + (DOI 10.3126/jist.v22i1.17745) [VERIFIED]: "The presence of Schreger line is the + identifying feature of an elephant tusk" — Schreger lines ABSENT in bone; Haversian + canals ABSENT in ivory. These are the definitive microscopical diagnostics. + SG 1.70-2.00 is lower than ivory (1.85-1.95; slight overlap). Hot-point: both give + "burnt bone" smell (not diagnostic for separating bone from ivory; but distinguishes + from plastic and vegetable ivory). CITES context: unlike elephant ivory, bone from + domestic animals has no trade restriction — but fraudulent substitution is an issue. +diagnostic_synthetic_features: > + Haversian canals (osteon/concentric ring microstructure around central channel; visible + at 10x-40x) PRESENT in bone; ABSENT in ivory; absence of Schreger lines in bone (ivory + has characteristic cross-hatch arcs at 100-130 degrees in cross-section); SG 1.70-2.00 + (slightly lower than ivory 1.85-1.95) +expressions: + - slug: default + name: Bone (carved; ivory simulant) + cdl: | + #! Species: Bone (biomineral; ivory simulant) + #! System: Amorphous (composite biomineral: apatite + collagen) + #! Habit: Massive; carved and polished + amorphous[waxy]:{massive} + is_primary: true + form_description: > + Domestic animal skeletal bone; composite biomineral (hydroxyapatite + collagen matrix). + Haversian canal microstructure (osteon system) visible under 10x-40x is the definitive + diagnostic distinguishing bone from ivory (which shows Schreger lines, not Haversian canals). + Included as gem material per FGA curriculum coverage of organic simulants. diff --git a/data/source/simulants/copal.yaml b/data/source/simulants/copal.yaml new file mode 100644 index 0000000..63be911 --- /dev/null +++ b/data/source/simulants/copal.yaml @@ -0,0 +1,47 @@ +id: copal +name: Copal (Amber Simulant) +crystal_system: amorphous +point_group: none +chemistry: Partially polymerised plant resin (labdanoid diterpenes; younger resin; not fully matured/polymerised) +category: amber simulant (natural material) +origin: simulant +target_minerals_json: '["amber"]' +year_first_produced: "0" +hardness: "1.5-2.5" +sg: "1.04-1.10" +ri: "1.530-1.545" +birefringence: 0 +optical_character: Isotropic +lustre: Resinous +cleavage: None +fracture: Conchoidal +colors: [Yellow to yellow-orange (similar to amber); pale yellow; transparent to translucent] +inclusions: [Modern insects (fresh appearance, not desiccated; diagnostic of recent origin); plant matter (less degraded than amber inclusions)] +fluorescence: Often intense (LWUV; typically brighter than amber, but variable) +notes: > + Partially polymerised plant resin (<40 Ma; often Holocene to Neogene); not fully matured. + Key distinction from amber: acetone test — copal becomes tacky/sticky within seconds; + amber (fully polymerised) is unaffected. FTIR: lacks the "Baltic shoulder" at ~1150 cm-1 + characteristic of mature succinite amber. Rao et al. 2013, Science China Physics, + Mechanics & Astronomy (DOI 10.1007/s11433-013-5144-z) [VERIFIED]: amber vs copal by + UV-VIS, infrared and Raman spectroscopy — acetone test and FTIR spectral fingerprint + confirmed as diagnostic. Commercial sources: Colombia, Madagascar, East Africa, New Zealand. + RI essentially identical to amber (1.530-1.545); SG overlaps amber (1.05-1.10); + refractometer and float tests cannot reliably distinguish — acetone and FTIR are required. +diagnostic_synthetic_features: > + Acetone test: surface becomes tacky/sticky in seconds (amber unaffected — definitive field + test); softens at lower temperature (~100-150 C vs amber ~200-250 C); FTIR lacks Baltic + amber "shoulder" ~1150 cm-1; inclusions appear fresh/undesiccated; surface crazing develops + faster; fluorescence often more intense than amber +expressions: + - slug: default + name: Copal + cdl: | + #! Species: Copal (partially polymerised plant resin; amber simulant) + #! System: Amorphous (natural resin) + #! Habit: Irregular nodular masses; resinous + amorphous[resinous]:{nodular} + is_primary: true + form_description: > + Partially polymerised plant resin; amorphous. Similar to amber in appearance but younger and + less polymerised. Acetone test (copal tacky; amber unaffected) is the definitive field test. diff --git a/data/source/simulants/dyed-howlite.yaml b/data/source/simulants/dyed-howlite.yaml new file mode 100644 index 0000000..8e161f8 --- /dev/null +++ b/data/source/simulants/dyed-howlite.yaml @@ -0,0 +1,49 @@ +id: dyed-howlite +name: Dyed Howlite (Turquoise Simulant) +crystal_system: monoclinic +point_group: 2/m +chemistry: Ca2B5SiO9(OH)5 (calcium borosilicate hydroxide; dyed blue to simulate turquoise) +category: turquoise simulant +origin: simulant +target_minerals_json: '["turquoise"]' +year_first_produced: "1960" +hardness: "3-3.5" +sg: "2.53-2.59" +ri: "1.583-1.608" +birefringence: 0.022 +optical_character: Biaxial - +lustre: Sub-vitreous to waxy +cleavage: None (but howlite is porous) +fracture: Conchoidal +colors: [Blue to blue-green (dyed); also sold undyed as white howlite] +inclusions: [Dye bleeding at fractures and vugs (diagnostic under loupe)] +fluorescence: Variable +notes: > + Howlite (Ca2B5SiO9(OH)5) is a natural calcium borosilicate hydroxide mineral; monoclinic 2/m. + When dyed blue it closely resembles turquoise. The dye is the simulant aspect. + Webster 1962, Journal of Gemmology 8(8):286 (DOI 10.15506/jog.1962.8.8.286) [VERIFIED]: + "A New Turquoise Simulant" — first documented dyed howlite as turquoise simulant. + Key diagnostics: (1) dye bleeding at fractures/vugs (visible under 10x loupe — natural + turquoise shows even colour); (2) hardness 3-3.5 (scratched by copper coin; turquoise H 5-6); + (3) acetone swab removes blue dye (natural turquoise colour is intrinsic); (4) FTIR shows + borosilicate spectrum (vs phosphate spectrum of turquoise); (5) birefringence 0.022 on flat + face (turquoise birefringence too small to observe). Also marketed as "white buffalo turquoise" + (undyed) or simply "turquoise" (when dyed). Primarily from California, USA and Canada. +diagnostic_synthetic_features: > + Dye bleeding at fractures and vugs under 10x loupe; hardness 3-3.5 (scratched by copper coin + vs turquoise H 5-6); acetone swab removes blue dye; FTIR borosilicate spectrum vs turquoise + phosphate; Chelsea filter reaction differs from natural turquoise; birefringence 0.022 measurable +expressions: + - slug: dyed + name: Dyed Howlite (Blue) + cdl: | + #! Species: Dyed Howlite (Ca2B5SiO9(OH)5; turquoise simulant) + #! System: Monoclinic (2/m) + #! Habit: Massive; porous; dye concentrates at fractures + monoclinic[2/m]:{010}@1.0 + {110}@0.5 + is_primary: true + form_description: > + Howlite (calcium borosilicate hydroxide; monoclinic 2/m) dyed blue to simulate turquoise. + Porous structure causes dye to concentrate at fractures and vugs (visible under loupe). + Much softer than turquoise (H 3-3.5 vs 5-6). Borosilicate FTIR spectrum vs turquoise + phosphate spectrum is definitive analytical distinction. diff --git a/data/source/simulants/dyed-magnesite.yaml b/data/source/simulants/dyed-magnesite.yaml new file mode 100644 index 0000000..149b56d --- /dev/null +++ b/data/source/simulants/dyed-magnesite.yaml @@ -0,0 +1,50 @@ +id: dyed-magnesite +name: Dyed Magnesite (Turquoise Simulant) +crystal_system: trigonal +point_group: "-3m" +chemistry: MgCO3 (magnesite; magnesium carbonate; dyed blue) +category: turquoise simulant +origin: simulant +target_minerals_json: '["turquoise"]' +year_first_produced: "1980" +hardness: "3.5-4.5" +sg: "2.98-3.05" +ri: "1.509-1.700" +birefringence: 0.191 +optical_character: Uniaxial - +lustre: Vitreous to pearly +cleavage: Perfect rhombohedral {1011} +fracture: Conchoidal +colors: [Blue to blue-green (dyed); white when undyed] +inclusions: [Dye bleeding at fractures and vugs] +fluorescence: Variable +notes: > + Natural magnesite (MgCO3) dyed blue to simulate turquoise; trigonal -3m (calcite structure + type). Produced primarily in China and Eastern Europe. No dedicated peer-reviewed DOI + resolved for dyed magnesite specifically; curriculum-standard simulant knowledge from + Read 7th ed. (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. Key diagnostic features: + (1) high birefringence 0.191 (vs turquoise which shows very low birefringence); refractometer + shows double shadow edge or two RI values (e~1.509, w~1.700) if flat face available; + (2) effervescence with warm dilute HCl (MgCO3 is a carbonate; turquoise phosphate does not + effervesce) — destructive but definitive; (3) dye bleeding at fractures; (4) acetone swab + removes dye; (5) FTIR carbonate spectrum (~1400 cm-1 strong CO3 absorption vs phosphate of + turquoise); (6) SG ~3.00 HEAVIER than turquoise 2.60-2.90 (opposite direction vs howlite). + Note: SG relationship is reversed from dyed howlite — magnesite sinks where turquoise and + howlite float in similar heavy liquids. +diagnostic_synthetic_features: > + Very high birefringence 0.191 (double shadow on refractometer; unique identifier); effervescence + in warm dilute HCl (carbonate vs phosphate turquoise); SG ~3.00 heavier than turquoise 2.60-2.90; + dye bleeding at fractures; acetone removes dye; FTIR carbonate absorption ~1400 cm-1 +expressions: + - slug: dyed + name: Dyed Magnesite (Blue) + cdl: | + #! Species: Dyed Magnesite (MgCO3; turquoise simulant) + #! System: Trigonal (-3m) + #! Habit: Massive granular; dyed blue + trigonal[-3m]:{10-10}@1.0 + {0001}@0.4 + is_primary: true + form_description: > + Magnesite (MgCO3; trigonal -3m; calcite-type structure) dyed blue to simulate turquoise. + Very high birefringence (0.191) is the most diagnostic refractometer feature. + Heavier than turquoise (SG ~3.00 vs 2.60-2.90). Effervesces in HCl (carbonate test). diff --git a/data/source/simulants/french-jet.yaml b/data/source/simulants/french-jet.yaml new file mode 100644 index 0000000..7dd9131 --- /dev/null +++ b/data/source/simulants/french-jet.yaml @@ -0,0 +1,47 @@ +id: french-jet +name: French Jet (Black Glass) +crystal_system: amorphous +point_group: none +chemistry: Soda-lime or lead glass; coloured black with iron oxide, manganese oxide, or carbon black; may be lead-rich for higher density and lustre +category: jet simulant +origin: simulant +target_minerals_json: '["jet"]' +year_first_produced: "1800" +hardness: "5-5.5" +sg: "2.40-3.50" +ri: "1.48-1.70" +birefringence: 0 +optical_character: Isotropic +lustre: Vitreous to brilliant +cleavage: None +fracture: Conchoidal +colors: [Uniform black (no brown tinge unlike vulcanite)] +inclusions: [Possible gas bubbles; conchoidal fracture on broken edges] +fluorescence: Variable +notes: > + Black glass jet simulant; popular 1840s-1900s for Victorian mourning jewellery. + "French jet" is primarily Bohemian and French glass industry production, not only French. + Key diagnostic: high SG 2.40-3.50 (jet = 1.30-1.35; French jet sinks rapidly in liquids + that float jet). Cold to touch (glass has high thermal conductivity). Conchoidal fracture + on broken edges. No smell on hot-point (vs jet = aromatic coal; vulcanite = sulfur/rubber). + Harder than jet (H 5-5.5 vs jet 2.5-4). Dictionary of Gems and Gemology (Springer) + (DOI 10.1007/978-3-540-72816-0_8882) [PARTIALLY_SUPPORTED — catalogue record only]. + Read 7th ed. p.330 (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. + VERIFIED.md status [PARTIALLY_SUPPORTED] per S-014. Included as curriculum-standard simulant. +diagnostic_synthetic_features: > + High SG 2.40-3.50 vs jet 1.30-1.35 (definitive hydrostatic test); cold to touch (glass + thermal conductivity); conchoidal fracture; no smell on hot-point; harder than jet; + possible gas bubbles under magnification; no organic microstructure (jet shows wood-grain) +expressions: + - slug: default + name: French Jet (Black Glass) + cdl: | + #! Species: French Jet (black glass; jet simulant) + #! System: Amorphous (glass) + #! Habit: Moulded/faceted black glass + amorphous[glassy]:{massive} + is_primary: true + form_description: > + Black glass (soda-lime or lead glass coloured with iron oxide, manganese, or carbon black). + Amorphous; isotropic. Very high SG (2.40-3.50) vs jet (1.30-1.35) is the primary diagnostic. + Cold to touch; conchoidal fracture; no hot-point smell. Victorian mourning jewellery simulant. diff --git a/data/source/simulants/reconstructed-turquoise.yaml b/data/source/simulants/reconstructed-turquoise.yaml new file mode 100644 index 0000000..4bc7633 --- /dev/null +++ b/data/source/simulants/reconstructed-turquoise.yaml @@ -0,0 +1,51 @@ +id: reconstructed-turquoise +name: Reconstructed Turquoise +crystal_system: triclinic +point_group: "-1" +chemistry: CuAl6(PO4)4(OH)8.4H2O (turquoise powder bound with PMMA acrylic or other resin binder) +category: turquoise simulant +origin: simulant +target_minerals_json: '["turquoise"]' +year_first_produced: "1970" +hardness: "4-5.5" +sg: "2.30-2.60" +ri: "1.61-1.65" +birefringence: null +optical_character: AGG +lustre: Waxy to sub-vitreous +cleavage: None (aggregate) +fracture: Conchoidal +colors: [Blue to blue-green (same turquoise colour range); may appear more uniform in colour than natural] +inclusions: [Matrix-like structure may appear uniform; polymer binder visible by FTIR] +fluorescence: Variable +notes: > + Reconstructed turquoise (also "reconstituted turquoise") is made from genuine turquoise + powder or low-quality turquoise material bound with a polymeric binder (commonly PMMA + acrylic). Chemistry given for the turquoise component (triclinic -1); the reconstruction + is the simulant aspect. Crystal system is triclinic (same as turquoise) but the material + is a composite powder + binder aggregate. Blumentritt et al. 2023, Journal of Gemmology + 38(5):443 (DOI 10.15506/jog.2023.38.5.443) [VERIFIED]: "A New Reconstructed Turquoise + Imitation Composed of Turquoise Powder with a PMMA (Acrylic) Binder" — documents + identification by FTIR (acrylic C-H bands distinct from natural turquoise). SG typically + lower than natural turquoise 2.60-2.90 (due to porous binder fill). FTIR is the primary + analytical tool: acrylic C-H stretching bands around 2950-3000 cm-1 are absent in natural + turquoise. Webster 1962 (DOI 10.15506/jog.1962.8.8.286) [VERIFIED] covers turquoise + simulants broadly. Property values (SG, RI) vary depending on binder fraction. +diagnostic_synthetic_features: > + FTIR: acrylic/PMMA C-H stretching bands ~2950-3000 cm-1 (absent in natural turquoise); + SG typically 2.30-2.60 (lower than natural turquoise 2.60-2.90 due to porous binder); + overly uniform colour distribution under magnification (vs natural colour distribution); + hot-point test: acrylic smell from binder +expressions: + - slug: default + name: Reconstructed Turquoise + cdl: | + #! Species: Reconstructed Turquoise (turquoise powder + PMMA binder) + #! System: Triclinic (-1; turquoise mineral phase) + #! Habit: Massive aggregate (powder + polymer binder) + triclinic[-1]:{010}@1.0 + {100}@0.6 + is_primary: true + form_description: > + Genuine turquoise powder bound with acrylic (PMMA) or other polymeric binder to form + a more homogeneous and workable material. Triclinic crystal system reflects the turquoise + mineral phase. FTIR detection of acrylic binder is the primary analytical method. diff --git a/data/source/simulants/slocum-stone.yaml b/data/source/simulants/slocum-stone.yaml new file mode 100644 index 0000000..0178501 --- /dev/null +++ b/data/source/simulants/slocum-stone.yaml @@ -0,0 +1,49 @@ +id: slocum-stone +name: Slocum Stone +crystal_system: amorphous +point_group: none +chemistry: Borosilicate glass with internal laminated metallic interference layers +category: opal simulant (glass-based) +origin: simulant +target_minerals_json: '["opal", "precious-opal"]' +manufacturer: John Slocum (USA); later Kyocera/Inamori produced similar imitation opal products +year_first_produced: "1974" +hardness: "5-5.5" +sg: "2.40-2.50" +ri: "1.48-1.52" +birefringence: 0 +optical_character: Isotropic +lustre: Vitreous +cleavage: None +fracture: Conchoidal +colors: [Colourless with metallic iridescent colour play (interference colours from metallic lamellae)] +inclusions: [Flat lath-like metallic laminae (critical; visible at 30-60x)] +fluorescence: None (glass; no OH absorption) +notes: > + Borosilicate glass with deposited thin metallic film laminations internally; proprietary + process. Directly API-verified: Farn 1979, Journal of Gemmology 16(5):295 + (DOI 10.15506/jog.1979.16.5.295) [VERIFIED]: "Imitation Opal — Slocum Stone" — metallic + lath/scaly appearance documented explicitly. Key diagnostic suite versus opal: (1) scaly + metallic laminae visible at 30-60x (vs mosaic patchwork of sphere stacks in natural opal + and Gilson synthetic opal); (2) high SG 2.40-2.50 vs natural opal 2.00-2.20 and Gilson + ~2.07 — hydrostatic SG measurement is immediately diagnostic; (3) no OH/water absorption + in FTIR (natural opal is hydrous 5-10% H2O; Slocum has none); (4) conchoidal fracture on + edges (glass substrate). Note on manufacturer: Slocum original patent 1974; Kyocera/Inamori + produced similar products. Target: precious opal (play-of-colour). +diagnostic_synthetic_features: > + Lath-like scaly metallic laminae visible at 30-60x magnification (vs mosaic sphere-stack + domains in natural and Gilson opal); high SG 2.40-2.50 (floats opal; sinks in di-iodomethane); + no FTIR OH absorption; glass substrate conchoidal fracture; no hot-point odour; isotropic +expressions: + - slug: default + name: Slocum Stone (Imitation Opal) + cdl: | + #! Species: Slocum Stone (borosilicate glass opal simulant) + #! System: Amorphous (glass) + #! Habit: Massive glass with internal metallic interference lamellae + amorphous[glassy]:{massive} | phenomenon[play_of_color:metallic_lamellae] + is_primary: true + form_description: > + Borosilicate glass with internal metallic film laminations producing iridescent colour play + mimicking precious opal. Metallic lath/scaly appearance under microscope is definitive. + High SG 2.40-2.50 immediately distinguishes from all opals. diff --git a/data/source/simulants/vulcanite.yaml b/data/source/simulants/vulcanite.yaml new file mode 100644 index 0000000..0074517 --- /dev/null +++ b/data/source/simulants/vulcanite.yaml @@ -0,0 +1,50 @@ +id: vulcanite +name: Vulcanite (Jet Simulant) +crystal_system: amorphous +point_group: none +chemistry: Sulfur-vulcanised natural rubber (polyisoprene cross-linked by S-S bonds; ~30-35% sulfur content in hard vulcanite/ebonite) +category: jet simulant +origin: simulant +target_minerals_json: '["jet"]' +manufacturer: Multiple 19th-early 20th century manufacturers (Victorian era jewellery production) +year_first_produced: "1843" +hardness: "2.5-3.5" +sg: "1.10-1.20" +ri: "1.66" +birefringence: 0 +optical_character: Isotropic +lustre: Brilliant to waxy +cleavage: None +fracture: Uneven +colors: [Black (body colour); brown surface tinge developing with age from sulfur oxidation] +inclusions: [Mould seams visible at edges (Victorian moulded pieces)] +fluorescence: Inert +notes: > + Vulcanisation process (rubber + sulfur heated under pressure) invented by Goodyear/Hancock + 1843; jewellery use 1850s-1920s for Victorian mourning jewellery as jet simulant. + Diagnostic: sulfurous/rubber smell on hot-point test (acrid; vs jet which gives aromatic + coal smell). Brown surface tinge from sulfur oxidation in old pieces (true jet stays black). + SG 1.10-1.20 lower than jet 1.30-1.35. RI ~1.66 (similar to jet; not diagnostic for + separation). Read 7th ed. pp.329-330 (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. + VERIFIED.md status [UNVERIFIED] for dedicated peer-reviewed paper — classified per S-013. + Included as curriculum-standard simulant (gemmological teaching content). + Key three-way separation: jet = aromatic coal smell + SG 1.30-1.35; vulcanite = sulfur/ + rubber smell + SG 1.10-1.20 + brown tinge; French jet = no smell + cold feel + SG 2.40-3.50. +diagnostic_synthetic_features: > + Sulfur/rubber smell on hot-point test (definitive vs jet coal smell); brown surface tinge + from oxidised sulfur (absent in jet and French jet); SG 1.10-1.20 (lower than jet 1.30-1.35); + warm to touch (low thermal conductivity); mould seams visible on Victorian pieces; + may brown with UV exposure +expressions: + - slug: default + name: Vulcanite (Hardened Rubber) + cdl: | + #! Species: Vulcanite (vulcanised rubber; jet simulant) + #! System: Amorphous (polymer) + #! Habit: Moulded masses; black with brown oxidation tinge + amorphous[resinous]:{massive} + is_primary: true + form_description: > + Sulfur-vulcanised natural rubber (ebonite); amorphous polymer. Victorian mourning jewellery + simulant for jet. Sulfurous rubber smell on hot-point is the definitive separation from jet. + Brown surface tinge from aging is characteristic. diff --git a/data/source/synthetics/synthetic-alexandrite-flux.yaml b/data/source/synthetics/synthetic-alexandrite-flux.yaml new file mode 100644 index 0000000..9d60644 --- /dev/null +++ b/data/source/synthetics/synthetic-alexandrite-flux.yaml @@ -0,0 +1,55 @@ +id: synthetic-alexandrite-flux +name: Flux-Grown Alexandrite +crystal_system: orthorhombic +point_group: mmm +chemistry: BeAl2O4:Cr +category: synthetic chrysoberyl +origin: synthetic +growth_method: flux (molybdate or vanadium-based flux solvent in platinum crucible; slow-cooling crystallisation) +natural_counterpart_id: alexandrite +manufacturer: Chatham Created Gems (San Francisco, USA); Creative Crystals Inc. (USA); Russian laboratory production +year_first_produced: "1964" +diagnostic_synthetic_features: > + Flux fingerprints (wispy veils following crystal growth sector boundaries; smoky diffuse + appearance — unlike natural fingerprints which follow healed fracture planes); platinum + platelets (flat hexagonal to irregular Pt metal from Pt crucible; bright mirror-like + under dark-field — highly diagnostic); flux feather inclusions (irregular solidified flux + masses); absence of twinning planes (natural Russian alexandrite shows polysynthetic + twinning); absence of natural inclusions (no negative crystals, no two-phase natural fluid + inclusions); Mo or V trace contamination from flux detectable by EDXRF +hardness: "8.5" +sg: "3.70-3.73" +ri: "1.746-1.755" +birefringence: 0.009-0.010 +optical_character: Biaxial + +dispersion: 0.015 +lustre: Vitreous +cleavage: Distinct {110} in two directions +fracture: Conchoidal +pleochroism: Strong trichroism +pleochroism_strength: strong +pleochroism_color1: Green (daylight/fluorescent) +pleochroism_color2: Red to purplish-red (incandescent) +colors: [Green (daylight), Red to purplish-red (incandescent)] +inclusions: [Flux fingerprints (wispy veils), Platinum platelets (Pt from crucible), Flux feather inclusions] +fluorescence: Moderate red (LW UV) +notes: > + Note: existing synthetic-alexandrite-czochralski.yaml already in DB; this file covers + the flux-grown variety only (Chatham/Creative Crystals). Do not confuse with Czochralski. + Schmetzer, Peretti, Medenbach & Bernhardt 1996, Gems & Gemology 32(3):186 + (DOI 10.5741/gems.32.3.186) [VERIFIED]: Russian flux-grown alexandrite diagnostics. + Platinum platelets are definitive — absent in all natural alexandrite. + Flux veils differ from natural fingerprints by their growth-sector relationship. + EDXRF: very low trace elements; Mo or V trace from flux; no significant Fe; no Ga. + Distinguishes from hydrothermal (chevron zoning + nail-head spicules) and Czochralski + (curved striae + iridium inclusions). +expressions: + - slug: crystal + name: Crystal + cdl: | + #! Species: Flux-Grown Alexandrite + #! System: Orthorhombic (mmm) + #! Habit: Tabular from flux growth + orthorhombic[mmm]:{110}@1.0 + {010}@0.7 + {001}@0.4 + is_primary: true + form_description: Tabular to prismatic crystal from flux growth in Pt crucible; contains characteristic flux veils and Pt platelets. diff --git a/data/source/synthetics/synthetic-alexandrite-hydrothermal.yaml b/data/source/synthetics/synthetic-alexandrite-hydrothermal.yaml new file mode 100644 index 0000000..c71129e --- /dev/null +++ b/data/source/synthetics/synthetic-alexandrite-hydrothermal.yaml @@ -0,0 +1,56 @@ +id: synthetic-alexandrite-hydrothermal +name: Hydrothermal Alexandrite +crystal_system: orthorhombic +point_group: mmm +chemistry: BeAl2O4:Cr +category: synthetic chrysoberyl +origin: synthetic +growth_method: hydrothermal (autoclave; aqueous mineraliser solution; seed plate of natural or synthetic chrysoberyl; growth over weeks at high T/P) +natural_counterpart_id: alexandrite +manufacturer: Tairus Joint Enterprise (Novosibirsk, Russia); Biron (Australia); Regency (Thailand/Australia) +year_first_produced: "1990" +diagnostic_synthetic_features: > + Chevron (herringbone) zoning — most characteristic growth feature; Cr colour zoning follows + chevron growth fronts of autoclave-grown crystal in a V-pattern parallel to seed plate; + visible under microscope with diffuse lighting; seed plate — visible (or implied by growth + geometry) junction between seed and overgrown material; nail-head spicules — short + nail-head-shaped two-phase inclusions (liquid + gas) oriented perpendicular to growth + layers; characteristic of hydrothermal growth under high pressure; absence of flux + inclusions (no Pt platelets; no flux veils — distinguishes from flux-grown); + wavy growth planes (hydrothermal growth planes visible as wavy parallel lines under + immersion); EDXRF: high purity; absence of Fe distinguishes from natural and Czochralski +hardness: "8.5" +sg: "3.70-3.73" +ri: "1.746-1.755" +birefringence: 0.009-0.010 +optical_character: Biaxial + +dispersion: 0.015 +lustre: Vitreous +cleavage: Distinct {110} in two directions +fracture: Conchoidal +pleochroism: Strong trichroism +pleochroism_strength: strong +pleochroism_color1: Green (daylight/fluorescent) +pleochroism_color2: Red to purplish-red (incandescent) +colors: [Green (daylight), Red to purplish-red (incandescent)] +inclusions: [Chevron growth zoning (Cr colour), Seed plate junction, Nail-head spicules (two-phase)] +fluorescence: Weak to moderate red (LW UV) +notes: > + Hydrothermal alexandrite from Tairus (Novosibirsk), Biron (Australia), and Regency. + Peretti, Mullis, Mouawad & Guggenheim 1997, Journal of Gemmology 25(8):540 + (DOI 10.15506/jog.1997.25.8.540) [VERIFIED]: inclusions in hydrothermal rubies and + sapphires from Tairus (Novosibirsk); diagnostic suite applies by analogy to hydrothermal + alexandrite from same manufacturer. Russian flux-grown alexandrite diagnostics confirmed + by Schmetzer et al. 1996 (DOI 10.5741/gems.32.3.186) [VERIFIED] for comparison. + Three-way distinction: Czochralski (curved striae + iridium inclusions); flux (Pt platelets + + flux veils); hydrothermal (chevron zoning + nail-head spicules + seed plate). +expressions: + - slug: crystal + name: Crystal + cdl: | + #! Species: Hydrothermal Alexandrite + #! System: Orthorhombic (mmm) + #! Habit: Tabular; chevron zoning from autoclave growth + orthorhombic[mmm]:{110}@1.0 + {010}@0.6 + {001}@0.3 + is_primary: true + form_description: Autoclave-grown crystal with chevron Cr zoning, nail-head spicules, and seed plate junction. diff --git a/data/source/synthetics/synthetic-emerald-lechleitner.yaml b/data/source/synthetics/synthetic-emerald-lechleitner.yaml new file mode 100644 index 0000000..ff6e18c --- /dev/null +++ b/data/source/synthetics/synthetic-emerald-lechleitner.yaml @@ -0,0 +1,62 @@ +id: synthetic-emerald-lechleitner +name: Lechleitner Emerald (Overgrowth) +crystal_system: hexagonal +point_group: 6/mmm +chemistry: Be3Al2Si6O18:Cr,V +category: synthetic emerald (overgrowth on natural seed) +origin: synthetic +growth_method: hydrothermal-overgrowth-on-natural-seed (synthetic hydrothermal Cr+V-rich beryl overgrowth deposited on natural colourless beryl seed — goshenite or pale aquamarine) +natural_counterpart_id: emerald +manufacturer: Johann Lechleitner (Innsbruck, Austria) +year_first_produced: "1960" +diagnostic_synthetic_features: > + Colourless beryl core visible under 10x loupe (transmitted light) — the most immediately + apparent feature; lighter colourless goshenite/aquamarine core visible inside green rim; + crackled interface — at junction between natural seed and synthetic hydrothermal overgrowth + a characteristic crackled or crazing texture develops ("crackled skin" in gemmological + literature); different inclusion suites in core vs overgrowth — natural beryl core retains + own inclusions (two-phase, growth tubes); synthetic skin shows hydrothermal features + (nail-head spicules, chevron zoning); Cr distribution concentrated in outer zone only + (Schmetzer et al. 1981 — Cr content analysis confirms synthetic origin of colouring layer); + UV fluorescence: mosaic or patchy response possible (natural core vs synthetic skin); + FTIR: seed beryl and overgrowth may show different water-related absorptions +hardness: "7.5-8" +sg: "2.67-2.72" +ri: "1.565-1.602" +birefringence: 0.006-0.009 +optical_character: Uniaxial - +dispersion: 0.014 +lustre: Vitreous +cleavage: Imperfect basal +fracture: Conchoidal +pleochroism: Strong dichroism +pleochroism_strength: strong +pleochroism_color1: Vivid green (ordinary ray) +pleochroism_color2: Bluish-green to colourless (extraordinary ray) +colors: [Vivid green (Cr + V chromophores in hydrothermal overgrowth)] +inclusions: [Colourless beryl core (diagnostic), Crackled interface between core and overgrowth, Natural inclusions in core; hydrothermal features (nail-head spicules) in synthetic skin] +fluorescence: Patchy UV response possible (core and overgrowth differ) +notes: > + CRITICAL CHEMISTRY FIX per VERIFIED.md Conflict 2 (F-01/REJ-02): R10 source listed + incorrect formula Be3Al2(SiO3)6:Cr+V — this is a chain-silicate notation and is + chemically incorrect for beryl (a cyclosilicate). Correct formula: Be3Al2Si6O18:Cr,V. + Applied here per mandatory correction. Multiple API-verified papers: Schmetzer, Bank & + Stahle 1981, Gems & Gemology 17(2):98 (DOI 10.5741/gems.17.2.98) [VERIFIED]: "The + Chromium Content of Lechleitner Synthetic Emerald Overgrowth" — Cr concentrated in outer + synthetic zone. Journal of Gemmology 1964 (DOI 10.15506/jog.1964.9.8.267) [VERIFIED]; + Eppler 1968 (DOI 10.15506/jog.1968.11.4.120) [VERIFIED]; Schmetzer & Bank 1988 + (DOI 10.15506/jog.1988.21.2.95) [VERIFIED]. Colourless core is definitive diagnostic + — absent in natural emerald. Crackled interface is definitive — absent in natural. +expressions: + - slug: crystal + name: Overgrowth Crystal + cdl: | + #! Species: Lechleitner Emerald (synthetic overgrowth on natural beryl seed) + #! System: Hexagonal (6/mmm) + #! Habit: Colourless natural beryl core with green synthetic hydrothermal skin + hexagonal[6/mmm]:{10-10}@1.0 + {0001}@0.6 > {10-10}@1.1 + {0001}@0.7 + is_primary: true + form_description: > + Natural colourless beryl (goshenite/aquamarine) seed with synthetic hydrothermal Cr+V-rich + beryl overgrowth. Nested CDL notation represents core (inner) and synthetic skin (outer). + Colourless core and crackled interface are definitive diagnostics. diff --git a/data/source/synthetics/synthetic-ruby-hydrothermal.yaml b/data/source/synthetics/synthetic-ruby-hydrothermal.yaml new file mode 100644 index 0000000..7d6a3d4 --- /dev/null +++ b/data/source/synthetics/synthetic-ruby-hydrothermal.yaml @@ -0,0 +1,57 @@ +id: synthetic-ruby-hydrothermal +name: Hydrothermal Ruby +crystal_system: trigonal +point_group: "-3m" +chemistry: Al2O3:Cr +category: synthetic corundum +origin: synthetic +growth_method: hydrothermal (autoclave; aqueous HF/chloride mineraliser; Cr dopant; seed plate of natural or synthetic corundum; 400-500 degrees C / >1 kbar) +natural_counterpart_id: ruby +manufacturer: Tairus Joint Enterprise (Novosibirsk, Russia); Biron (Perth, Australia) +year_first_produced: "1985" +diagnostic_synthetic_features: > + Hexagonal seed plate — clearly visible junction between seed crystal and hydrothermal + overgrowth; the seed may have different colour intensity or inclusion suite; plate is + typically hexagonally oriented parallel to c-axis of corundum; chevron (herringbone) Cr + zoning — Cr colour distributed in chevron-pattern waves perpendicular to growth direction; + two-phase inclusions (feathers) — liquid + gas forming irregular feather patterns; differ + from natural marble-hosted ruby feathers (which contain calcite or apatite daughters); + nail-head spicules — short perpendicular needles with rounded heads from hydrothermal + overpressure; absence of natural ruby inclusions (no rutile silk, no calcite, no apatite, + no zircon, no natural negative crystals); trace element: very low Fe (<50 ppm typically; + natural ruby always >100 ppm Fe); occasionally Nb trace from autoclave walls +hardness: "9" +sg: "3.99-4.01" +ri: "1.762-1.770" +birefringence: 0.008 +optical_character: Uniaxial - +dispersion: 0.018 +lustre: Vitreous to adamantine +cleavage: None (parting on {0001} and {10-11}) +fracture: Conchoidal +pleochroism: Strong dichroism +pleochroism_strength: strong +pleochroism_color1: purplish-red +pleochroism_color2: orangey-red +colors: [Red, Pinkish-red] +inclusions: [Hexagonal seed plate junction, Chevron Cr colour zoning, Nail-head spicules (two-phase), Two-phase fluid feathers] +fluorescence: Strong red (LW and SW UV; same as natural Burma ruby) +notes: > + Hydrothermal ruby from Tairus (Novosibirsk) and Biron (Perth). Two API-verified papers: + Peretti et al. 1997, Journal of Gemmology 25(8):540 (DOI 10.15506/jog.1997.25.8.540) + [VERIFIED]: inclusions in hydrothermal rubies from Tairus; seed plate, nail-head spicules, + chevron zoning documented. Muhlmeister et al. 1998, Gems & Gemology 34(2):80 + (DOI 10.5741/gems.34.2.80) [VERIFIED]: "Hydrothermal rubies can be separated from natural + rubies by their low iron content and by trace amounts of niobium that are sometimes present + from the autoclave walls." Distinguishes from Kashan flux ruby (Pt platelets, angular flux + masses, Mo trace) and from Verneuil (curved striae, gas bubbles). +expressions: + - slug: crystal + name: Crystal + cdl: | + #! Species: Hydrothermal Ruby + #! System: Trigonal (-3m) + #! Habit: Tabular to prismatic; seed plate base; chevron Cr zoning + trigonal[-3m]:{10-10}@1.0 + {10-11}@0.8 + {0001}@0.5 + is_primary: true + form_description: Autoclave-grown ruby with hexagonal seed plate junction, chevron Cr colour zoning, and nail-head spicule inclusions. diff --git a/data/source/synthetics/synthetic-ruby-kashan-flux.yaml b/data/source/synthetics/synthetic-ruby-kashan-flux.yaml new file mode 100644 index 0000000..25741ba --- /dev/null +++ b/data/source/synthetics/synthetic-ruby-kashan-flux.yaml @@ -0,0 +1,61 @@ +id: synthetic-ruby-kashan-flux +name: Kashan Flux Ruby +crystal_system: trigonal +point_group: "-3m" +chemistry: Al2O3:Cr +category: synthetic corundum +origin: synthetic +growth_method: flux (molybdate-based flux in platinum crucible; slow-cooling crystallisation; independently developed from Chatham process) +natural_counterpart_id: ruby +manufacturer: Kashan Inc. (produced 1968-1996; associated with Inamori/Kyocera technology) +year_first_produced: "1968" +diagnostic_synthetic_features: > + Angular flux fingerprints (Kashan flux residue forms angular, more geometric fingerprint + textures rather than the wispy cloud-like veils of Chatham/Knischka — angular, partially + solidified flux inclusions visible under dark-field illumination); platinum platelets + (flat hexagonal to irregular Pt metal from Pt crucible; same as other Pt-crucible flux + products; diagnostic for all flux-grown corundum); absence of twinning (Kashan rubies + rarely show polysynthetic twinning lamellae typical of natural Burmese ruby); absence of + rutile silk (no fine straight rutile needles as in natural Mogok ruby); molybdenum trace + (Mo from flux detectable by EDXRF; natural ruby has no Mo; highly diagnostic chemical + signature); strong Cr fluorescence (both LWUV and SWUV; intense red from pure Cr3+ + environment; natural Burma ruby also strong, but combination with Mo trace and Pt platelets + is conclusive); absorption spectrum shows strong doublet at 692/694 nm (Cr3+ R-lines); + no 450 nm Fe band (natural ruby often has Fe-related absorption at 450 nm from Thai/Cambodian origin) +hardness: "9" +sg: "3.99-4.01" +ri: "1.762-1.770" +birefringence: 0.008 +optical_character: Uniaxial - +dispersion: 0.018 +lustre: Vitreous to adamantine +cleavage: None (parting on {0001} and {10-11}) +fracture: Conchoidal +pleochroism: Strong dichroism +pleochroism_strength: strong +pleochroism_color1: purplish-red +pleochroism_color2: orangey-red +colors: [Red, Pinkish-red] +inclusions: [Angular flux fingerprints (geometric; Kashan-specific), Platinum platelets, Absence of rutile silk] +fluorescence: Very strong red (LW and SW UV; characteristic of pure Cr3+ environment) +notes: > + Kashan flux ruby distinguishes from generic flux ruby (Chatham/Knischka/Ramaura) by angular + flux fingerprint geometry (Chatham = wispy veils); from generic flux ruby.yaml in DB. + Two API-verified papers: Burch 1984, Journal of Gemmology 19(1):54 + (DOI 10.15506/jog.1984.19.1.54) [VERIFIED]: "Some Observations on a Kashan Synthetic Ruby" + — Pt platelets and angular flux fingerprints documented. Muhlmeister et al. 1998, + Gems & Gemology 34(2):80 (DOI 10.5741/gems.34.2.80) [VERIFIED]: "flux-grown rubies in + general show extremely strong red fluorescence under both longwave and shortwave UV." + Mo trace by EDXRF: absent in natural ruby — chemical confirmation. Production 1968-1996; + Inamori (Kyocera) technology. Distinguishes from hydrothermal (no Pt, chevron zoning) + and from Verneuil (curved striae, gas bubbles, no Pt). +expressions: + - slug: crystal + name: Crystal + cdl: | + #! Species: Kashan Flux Ruby + #! System: Trigonal (-3m) + #! Habit: Tabular to prismatic from Pt-crucible flux growth + trigonal[-3m]:{10-10}@1.0 + {10-11}@0.8 + {0001}@0.5 + is_primary: true + form_description: Flux-grown ruby in Pt crucible; angular flux fingerprints and Pt platelets are diagnostic; Mo trace by EDXRF is confirmatory. diff --git a/data/source/synthetics/synthetic-sapphire-czochralski.yaml b/data/source/synthetics/synthetic-sapphire-czochralski.yaml new file mode 100644 index 0000000..b1b77a2 --- /dev/null +++ b/data/source/synthetics/synthetic-sapphire-czochralski.yaml @@ -0,0 +1,54 @@ +id: synthetic-sapphire-czochralski +name: Czochralski Sapphire +crystal_system: trigonal +point_group: "-3m" +chemistry: Al2O3 +category: synthetic corundum +origin: synthetic +growth_method: Czochralski (melt pulling; seed rod pulled upward from melt surface under rotation) +natural_counterpart_id: sapphire +manufacturer: Linde Division (Union Carbide, USA); Kyocera Corp. (Japan); Crystal Systems Inc.; Rubicon Technology; Saint-Gobain +year_first_produced: "1958" +diagnostic_synthetic_features: > + Tight curved growth striae (finer and more closely spaced than Verneuil; concentric arcs + around growth axis under immersion); absence of gas-bubble trains (characteristic of + Verneuil but absent in Czochralski); absence of curved colour banding; platinum-group + metal (PGM) rod-like inclusions from seed holder (highly diagnostic of Linde boules); + no natural inclusion suite (no rutile silk, no zircon, no negative crystals); Linde star + sapphire: artificially precipitated rutile needles (too perfect and uniformly spaced under + magnification; typically on flat-back synthetic dome) +hardness: "9" +sg: "3.99-4.01" +ri: "1.762-1.770" +birefringence: 0.008 +optical_character: Uniaxial - +dispersion: 0.018 +lustre: Vitreous to adamantine +cleavage: None (parting on {0001} and {10-11}) +fracture: Conchoidal +pleochroism: Weak dichroism (same as natural corundum) +pleochroism_strength: weak +pleochroism_color1: Blue +pleochroism_color2: Pale blue to colourless +colors: [Blue, Colourless, Various (by doping)] +inclusions: [Tight curved growth striae, Platinum-group metal rod inclusions (PGM from seed holder), Absence of natural inclusions (no rutile silk)] +fluorescence: Weak to inert (Linde blue may show weak orange-red under SWUV) +notes: > + Czochralski sapphire grown from melt pulled upward on rotating seed rod; produces a boule + rather than Verneuil pear-shaped boule. Key distinction from Verneuil: tighter curved striae + (vs broader curves in Verneuil); no gas-bubble trains; PGM inclusions from seed holder. + EDXRF/LA-ICP-MS: extremely low trace elements (Ga typically below detection in natural + sapphire >1 ppm). Linde star ruby/sapphire: Ti-doped then annealed to precipitate rutile. + Gemmological properties and growth method from Read 7th ed. pp.193-195 + (DOI 10.4324/9780080507224) [PARTIALLY_SUPPORTED]. No dedicated peer-reviewed + gemmological paper for Czochralski sapphire identification retrieved via API. +expressions: + - slug: crystal + name: Crystal + cdl: | + #! Species: Czochralski Sapphire + #! System: Trigonal (-3m) + #! Habit: Cylindrical boule with prismatic habit + trigonal[-3m]:{10-10}@1.0 + {10-11}@0.8 + {0001}@0.5 + is_primary: true + form_description: Czochralski-pulled boule; prismatic to cylindrical crystal from melt pulling process. diff --git a/src/mineral_database/data/minerals.db b/src/mineral_database/data/minerals.db index 85ebe33..e2d6df7 100644 Binary files a/src/mineral_database/data/minerals.db and b/src/mineral_database/data/minerals.db differ