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ASE → RMG Thermochemistry Pipeline for Surface Adsorbates

This repository contains a set of notebooks and helper scripts for converting DFT/ASE outputs for surface adsorbates into RMG-compatible thermochemistry libraries using NASA polynomials.

The workflow takes:

  • ASE trajectory files
  • Vibrational frequencies + ZPE from DFT
  • Generates per-species thermo
  • Fits NASA polynomials
  • Produces RMG thermo library entries

Dependencies

Core requirements:

  • Python ≥ 3.8
  • NumPy
  • SciPy
  • Pandas
  • Matplotlib
  • ASE (Atomic Simulation Environment)

Workflow Overview

  1. Preprocess DFT outputs

Run: standardize_inputs.ipynb

This prepares:

  • standardized trajectory names
  • vibrational + ZPE logs

  1. Generate NASA polynomials and convert to RMG format

Run: compute_NASA_for_<surface>-adsorbates.ipynb

This generates an RMG-ready thermo library.

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